Nickel catalyzed olefin oligomerization and dimerization

H Olivier-Bourbigou, PAR Breuil, L Magna… - Chemical …, 2020 - ACS Publications
Brought to life more than half a century ago and successfully applied for high-value
petrochemical intermediates production, nickel-catalyzed olefin oligomerization is still a very …

Converting olefins to propene: Ethene to propene and olefin cracking

V Blay, E Epelde, R Miravalles, LA Perea - Catalysis Reviews, 2018 - Taylor & Francis
Demand for propene as a petrochemical building block keeps growing, while its availability
has been decreased by the adoption of shale gas resources, among others. Efforts to …

Ethylene oligomerization on nickel catalysts on a solid acid support: From New mechanistic insights to tunable bifunctionality

E Koninckx, PSF Mendes, JW Thybaut… - Applied Catalysis A …, 2021 - Elsevier
Light alkene oligomerization on heterogeneous acidic catalysts is widely and successfully
used in current commercial processes. However, ethylene oligomerization remains …

Stable and selective conversion of ethylene to propylene and butylene using Ni-loaded dealuminated Beta zeolite catalyst

H Kitamura, T Sumi, S Kubota, S Kokuryo… - Applied Catalysis A …, 2023 - Elsevier
The selective conversion of ethylene into propylene (ETP) has garnered significant attention
due to the growing demand for the product of this reaction in the petrochemical industry. In …

Hydrocarbon pool mechanism of the zeolite-catalyzed conversion of ethene to propene

K Lee, SB Hong - ACS Catalysis, 2019 - ACS Publications
In order to detail the hydrocarbon pool mechanism of the zeolite-catalyzed ethene to
propene (ETP) conversion, ethene conversion was conducted over H-UZM-35 zeolite in the …

Specific localization of aluminum sites favors ethene-to-propene conversion on (Al) MCM-41-supported Ni (II) single sites

IB Moroz, A Lund, M Kaushik, L Severy, D Gajan… - ACS …, 2019 - ACS Publications
Single-site Ni (II) catalytic centers supported on MCM-41-type materials were prepared via
surface organometallic chemistry using tailored thermolytic molecular precursors. These …

Direct transformation of butenes or ethylene into propylene by cascade catalytic reactions

V Hulea - Catalysis Science & Technology, 2019 - pubs.rsc.org
This perspective focuses on the production of propylene from n-butenes or ethylene only in
catalytic cascade reactions. The studies reviewed here demonstrated that in a single reactor …

Polyfunctional catalysis in conversion of light alkenes

TR Karpova, AV Lavrenov, EA Buluchevskii… - Russian Chemical …, 2023 - Springer
Light alkenes are among the main petrochemical intermediate products, the consumption of
which is steadily growing. Using ethylene as an example, the possibilities of using …

Study of reaction network of the ethylene-to-propene reaction by means of isotopically labelled reactants

U Rodemerck, EV Kondratenko, M Stoyanova… - Journal of catalysis, 2020 - Elsevier
The reaction mechanism of the direct conversion of ethylene to propene over Ni-containing
catalysts is assumed in literature to comprise (i) ethylene dimerization to 1-butene,(ii) butene …

Propene production at low temperature by bimetallic Ni-Mo and Ni-Re catalysts on mesoporous MCM-41 prepared using template ion exchange

LA Perea, M Felischak, T Wolff, JAL Gaona, C Hamel… - Fuel, 2021 - Elsevier
In this work the direct conversion of ethene to propene was carried out using bimetallic Ni-
Mo and Ni-Re over MCM-41 and aluminized MCM-41. It was intended to improve typical Ni …