This review summarizes the advancements in rhodium-catalyzed asymmetric C–H
functionalization reactions during the last two decades. Parallel to the rapidly developed …

Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …

Enantioselective redox transformations typically rely on costly transition metals as catalysts
and often stoichiometric amounts of chemical redox agents as well. Electrocatalysis …

Conspectus Carbon dioxide (CO2) is recognized as a greenhouse gas and a common
waste product. Simultaneously, it serves as an advantageous and commercially available …

The asymmetric difunctionalization of alkenes, a method transforming readily accessible
alkenes into enantioenriched chiral structures of high value, has long been a focal point of …

Electrochemistry, which employs electrons as reagents and avoids the use of traditional
redox reagents, becomes a powerful tool in oxidative dehydrogenation cross-coupling …

Herein, a facile and general electroreductive deuteration of unactivated alkyl halides (X= Cl,
Br, I) or pseudo-halides (X= OMs) using D2O as the economical deuterium source was …

Despite widespread use of the deuterium isotope effect, selective deuterium labeling of
chemical molecules remains a major challenge. Herein, a facile and general …

The oxygen evolution reaction (OER), characterized by a four‐electron transfer kinetic
process, represents a significant bottleneck in improving the efficiency of hydrogen …

Carboxylation of easily available alkenes with CO2 is highly important to afford value‐added
carboxylic acids. Although dicarboxylation of activated alkenes, especially 1, 3‐dienes, has …