Achieving large thermal hysteresis in an anthracene-based manganese (II) complex via photo-induced electron transfer
JX Hu, Q Li, HL Zhu, ZN Gao, Q Zhang, T Liu… - Nature …, 2022 - nature.com
Achieving magnetic bistability with large thermal hysteresis is still a formidable challenge in
material science. Here we synthesize a series of isostructural chain complexes using 9, 10 …
material science. Here we synthesize a series of isostructural chain complexes using 9, 10 …
Hydrogen-bonded framework of a cobalt (II) complex showing superior stability and field-induced slow magnetic relaxation
A unique hydrogen-bonded organic–inorganic framework (HOIF) constructed from a
mononuclear cobalt (II) complex,[Co (MCA) 2·(H2O) 2](HMCA= 4-imidazolecarboxylic acid) …
mononuclear cobalt (II) complex,[Co (MCA) 2·(H2O) 2](HMCA= 4-imidazolecarboxylic acid) …
Tunable valence tautomerism in lanthanide–organic alloys
MA Dunstan, AS Manvell, NJ Yutronkie, F Aribot… - Nature Chemistry, 2024 - nature.com
The inimitable electronic structures of the lanthanide (Ln) ions are key to advanced materials
and technologies involving these elements. The trivalent ions are ubiquitous and are used …
and technologies involving these elements. The trivalent ions are ubiquitous and are used …
Copper-Iodide Hybrid Clusters with Partial Distortion Enable High-Performance Full-Visible-Spectrum White-Light-Emitting Diodes
KH Song, M Peng, JJ Wang, LZ Feng… - Journal of the …, 2024 - ACS Publications
Phosphor-converted white-light-emitting diodes (pc-WLEDs) have become increasingly
prevalent artificial light sources. Currently, multicomponent phosphors are commonly used …
prevalent artificial light sources. Currently, multicomponent phosphors are commonly used …
Tracking C–H activation with orbital resolution
Transition metal reactivity toward carbon–hydrogen (C–H) bonds hinges on the interplay of
electron donation and withdrawal at the metal center. Manipulating this reactivity in a …
electron donation and withdrawal at the metal center. Manipulating this reactivity in a …
δ-Bonding modulates the electronic structure of formally divalent nd 1 rare earth arene complexes
RE MacKenzie, T Hajdu, JA Seed, GFS Whitehead… - Chemical …, 2024 - pubs.rsc.org
Landmark advances in rare earth (RE) chemistry have shown that divalent complexes can
be isolated with non-Aufbau 4fn {5d/6s} 1 electron configurations, facilitating remarkable …
be isolated with non-Aufbau 4fn {5d/6s} 1 electron configurations, facilitating remarkable …
Two Cd-Based Coordination Frameworks Assembled with the Tri (pyridine-3-yl) amine: Structures, Room-Temperature Phosphorescence, and Photochromism
XM **g, SZ Li, Y Lang, XX Liang, A Wang… - Crystal Growth & …, 2024 - ACS Publications
The synthesis of two three-dimensional coordination frameworks [CdX2 (TPA)](X= Br for 1
and I for 2) has been achieved through the assembly of tri (pyridine-3-yl) amine (TPA) with …
and I for 2) has been achieved through the assembly of tri (pyridine-3-yl) amine (TPA) with …
Fast and tunable phosphorescence from organic ionic crystals
I Partanen, O Al‐Saedy, T Eskelinen… - Angewandte …, 2023 - Wiley Online Library
Crystalline diphosphonium iodides [MeR2P‐spacer‐R2Me] I with phenylene (1, 2),
naphthalene (3, 4), biphenyl (5) and anthracene (6) as aromatic spacers, are photoemissive …
naphthalene (3, 4), biphenyl (5) and anthracene (6) as aromatic spacers, are photoemissive …
Incorporation of a Fluorine Atom in a Bridging Ligand of Half-Lantern PtII2 Complexes Provides up to 10-Fold Enhancement of Electroluminescence Brightness
EA Katlenok, DM Kryukov, AE Kurtsevich… - Inorganic …, 2023 - ACS Publications
The binuclear half-lantern platinum (II) complexes [Pt (pbt)(μ-S∧ N)] 2 (pbtH= 2-
phenylbenzothiazole, S∧ N= benzo [d] thiazole-2-thiolate Pt1, 6-fluorobenzo [d] thiazole-2 …
phenylbenzothiazole, S∧ N= benzo [d] thiazole-2-thiolate Pt1, 6-fluorobenzo [d] thiazole-2 …
Radicalizing CO by Mononuclear Palladium (I)
T Bruckhoff, J Ballmann… - Angewandte Chemie …, 2024 - Wiley Online Library
A mononuclear, T‐shaped palladium (I) d9 metalloradical (3), stabilized by a bulky
carbazole‐based PNP‐ligand, was obtained by reduction of palladium chloride or thermal …
carbazole‐based PNP‐ligand, was obtained by reduction of palladium chloride or thermal …