Breaking Barriers in Chalcogenide Perovskite Synthesis: A Generalized Framework for Fabrication of BaMS3 (M═Ti, Zr, Hf) Materials

S Agarwal, KC Vincent, JW Turnley… - Advanced Functional …, 2024 - Wiley Online Library
Chalcogenide perovskites have garnered increasing attention as stable, non‐toxic
alternatives to lead halide perovskites. However, their conventional synthesis at high …

Expanding the horizons for viable precursors and liquid fluxes for the synthesis of BaZrS 3 and related compounds

KC Vincent, S Agarwal, Z Fan… - Journal of Materials …, 2024 - pubs.rsc.org
Chalcogenide perovskites represent a prominent class of emerging semiconductor materials
for photovoltaic applications, boasting excellent optoelectronic properties, appropriate …

Advances in chalcogenide perovskites: Fundamentals and applications

Y Han, X Fang, Z Shi - Applied Physics Reviews, 2024 - pubs.aip.org
Chalcogenide perovskites are a family of compounds related to perovskite structures or
compositions, which have witnessed rapid advances in recent years. They possess …

From synthesis to application: a review of BaZrS 3 chalcogenide perovskites

S Agarwal, KC Vincent, R Agrawal - Nanoscale, 2025 - pubs.rsc.org
Chalcogenide perovskites are gaining prominence as earth-abundant and non-toxic solar
absorber materials, crystallizing in a distorted perovskite structure. Among these, BaZrS3 …

Quantitative Scales for Haliphilicity of Metals: Tailoring the Halide Affinity of Alkaline Earth Metals to Synthesize Chalcogenide Perovskite BaMS3 (M = Zr, and Hf) and Cu2 …

S Agarwal, KC Vincent, R Agrawal - ACS Applied Energy Materials, 2024 - ACS Publications
Chalcogenide semiconductors, such as BaMS3 (M= Zr and Hf) and Cu2BaSnS4, have
attracted growing interest due to the constituent elements' abundance and reported …

Rethinking tolerance factor analysis for chalcogenide perovskites

JW Turnley, S Agarwal, R Agrawal - Materials Horizons, 2024 - pubs.rsc.org
Tolerance factor analysis has been widely used to predict suitable compositions for oxide
and halide perovskites. However, in the case of the emerging chalcogenide perovskites, the …

A reliable, colloidal synthesis method of the orthorhombic chalcogenide perovskite, BaZrS 3, and related ABS 3 nanomaterials (A= Sr, Ba; B= Ti, Zr, Hf): a step forward …

DC Hayes, S Agarwal, KC Vincent, IM Aimiuwu… - Chemical …, 2025 - pubs.rsc.org
Recently, chalcogenide perovskites, of the form ABX3, where typically A= alkaline earth
metals Ca, Sr, or Ba; B= group IV transition metals Zr or Hf; and X= chalcogens S or Se, have …

Emergence of Ruddlesden–Popper phases and other pitfalls for moderate temperature solution deposited chalcogenide perovskites

AA Pradhan, S Agarwal, KC Vincent… - Materials Chemistry …, 2024 - pubs.rsc.org
Chalcogenide perovskites have recently attracted significant attention for renewable energy
applications due to their predicted combination of air, moisture, and thermal stability, which …

Solution processed metal chalcogenide semiconductors for inorganic thin film photovoltaics

JW Turnley, R Agrawal - Chemical Communications, 2024 - pubs.rsc.org
Thin film photovoltaics are a key part of both current and future solar energy technologies
and have been heavily reliant on metal chalcogenide semiconductors as the absorber layer …

Charge Transport and Defects in Sulfur-Deficient Chalcogenide Perovskite BaZrS

G Aggarwal, AS Mirza, S Riva, C Comparotto… - arxiv preprint arxiv …, 2024 - arxiv.org
Exploring the conduction mechanism in the chalcogenide perovskite BaZrS $ _3 $ is of
significant interest due to its potential suitability as a top absorber layer in silicon-based …