Sequence-specific DNA binding Pyrrole–imidazole polyamides and their applications

Y Kawamoto, T Bando, H Sugiyama - Bioorganic & medicinal chemistry, 2018‏ - Elsevier
Abstract Pyrrole–imidazole polyamides (Py–Im polyamides) are cell-permeable compounds
that bind to the minor groove of double-stranded DNA in a sequence-specific manner …

Programmable DNA-binding small molecules

MS Blackledge, C Melander - Bioorganic & medicinal chemistry, 2013‏ - Elsevier
Aberrant gene expression is responsible for a myriad of human diseases from infectious
diseases to cancer. Precise regulation of these genes via specific interactions with the DNA …

Fluorescein redirects a ruthenium− octaarginine conjugate to the nucleus

CA Puckett, JK Barton - Journal of the American Chemical Society, 2009‏ - ACS Publications
The cellular uptake and localization of a Ru− octaarginine conjugate with and without an
appended fluorescein are compared. The inherent luminescence of the Ru (II) …

Inhibition of vascular endothelial growth factor with a sequence-specific hypoxia response element antagonist

BZ Olenyuk, GJ Zhang, JM Klco… - Proceedings of the …, 2004‏ - National Acad Sciences
Vascular endothelial growth factor (VEGF) and its receptors have been implicated as key
factors in tumor angiogenesis that are up-regulated by hypoxia. We evaluated the effects of …

Allosteric modulation of DNA by small molecules

DM Chenoweth, PB Dervan - Proceedings of the National …, 2009‏ - National Acad Sciences
Many human diseases are caused by dysregulated gene expression. The oversupply of
transcription factors may be required for the growth and metastatic behavior of human …

Rational design of ligands targeting triplet repeating transcripts that cause RNA dominant disease: application to myotonic muscular dystrophy type 1 and …

A Pushechnikov, MM Lee… - Journal of the …, 2009‏ - ACS Publications
Herein, we describe the design of high affinity ligands that bind expanded rCUG and rCAG
repeat RNAs expressed in myotonic dystrophy type 1 (DM1) and spinocerebellar ataxia type …

Modulation of NF-κB-dependent gene transcription using programmable DNA minor groove binders

JA Raskatov, JL Meier, JW Puckett… - Proceedings of the …, 2012‏ - National Acad Sciences
Nuclear factor κB (NF-κB) is a transcription factor that regulates various aspects of immune
response, cell death, and differentiation as well as cancer. In this study we introduce the Py …

DNA sequence-specific polyamides alleviate transcription inhibition associated with long GAA· TTC repeats in Friedreich's ataxia

R Burnett, C Melander, JW Puckett… - Proceedings of the …, 2006‏ - National Acad Sciences
The DNA abnormality found in 98% of Friedreich's ataxia (FRDA) patients is the unstable
hyperexpansion of a GAA· TTC triplet repeat in the first intron of the frataxin gene. Expanded …

Anticancer Activities of DNA-Alkylating Pyrrole–Imidazole Polyamide Analogs Targeting RUNX Transcription Factors against p53-Mutated Pancreatic Cancer PANC-1 …

Y Hirose, S Sato, K Hashiya, T Bando… - Journal of Medicinal …, 2023‏ - ACS Publications
The runt-related transcription factor (RUNX) family is known to play important roles in the
progression of cancer. Conjugate 1, which covalently binds to the RUNX-binding …

Hoechst tagging: a modular strategy to design synthetic fluorescent probes for live-cell nucleus imaging

A Nakamura, K Takigawa, Y Kurishita… - Chemical …, 2014‏ - pubs.rsc.org
We report a general strategy to create small-molecule fluorescent probes for the nucleus in
living cells. Our strategy is based on the attachment of the DNA-binding Hoechst compound …