Metal–organic frameworks in heterogeneous catalysis: recent progress, new trends, and future perspectives
More than 95%(in volume) of all of today's chemical products are manufactured through
catalytic processes, making research into more efficient catalytic materials a thrilling and …
catalytic processes, making research into more efficient catalytic materials a thrilling and …
Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …
(MOFs) together with the facile tunability of their properties makes these materials suitable …
Surface coordination chemistry of atomically dispersed metal catalysts
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …
catalysts, have been widely investigated during the past two decades. The atomic dispersion …
Catalysis by metal organic frameworks: perspective and suggestions for future research
Metal organic frameworks (MOFs) have drawn wide attention as potential catalysts, offering
high densities of catalytic sites in high-area porous solids, some with stabilities at high …
high densities of catalytic sites in high-area porous solids, some with stabilities at high …
Defect engineering: tuning the porosity and composition of the metal–organic framework UiO-66 via modulated synthesis
Presented in this paper is a deep investigation into the defect chemistry of UiO-66 when
synthesized in the presence of monocarboxylic acid modulators under the most commonly …
synthesized in the presence of monocarboxylic acid modulators under the most commonly …
Modulating coordination environment of single-atom catalysts and their proximity to photosensitive units for boosting MOF photocatalysis
Well-organized photosensitive units and catalytic sites in proximity are crucial for improving
charge separation efficiency and boosting photocatalysis. Herein, a general and facile …
charge separation efficiency and boosting photocatalysis. Herein, a general and facile …
Secondary building units as the turning point in the development of the reticular chemistry of MOFs
The secondary building unit (SBU) approach was a turning point in the discovery of
permanently porous metal-organic frameworks (MOFs) and in launching the field of reticular …
permanently porous metal-organic frameworks (MOFs) and in launching the field of reticular …
Machine learning the quantum-chemical properties of metal–organic frameworks for accelerated materials discovery
The modular nature of metal–organic frameworks (MOFs) enables synthetic control over
their physical and chemical properties, but it can be difficult to know which MOFs would be …
their physical and chemical properties, but it can be difficult to know which MOFs would be …
Metal–organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents
Owing to the vast diversity of linkers, nodes, and topologies, metal–organic frameworks can
be tailored for specific tasks, such as chemical separations or catalysis. Accordingly, these …
be tailored for specific tasks, such as chemical separations or catalysis. Accordingly, these …
Destruction of chemical warfare agents using metal–organic frameworks
Chemical warfare agents containing phosphonate ester bonds are among the most toxic
chemicals known to mankind. Recent global military events, such as the conflict and …
chemicals known to mankind. Recent global military events, such as the conflict and …