Infrared spectroscopy of organometallic ions in the gas phase: from model to real world complexes

L MacAleese, P Maître - Mass Spectrometry Reviews, 2007 - Wiley Online Library
Gas phase mid‐infrared spectroscopy of molecular ions can nowadays be performed with
high performance mass spectrometers coupled to free electron lasers (FEL). The wide and …

Characterization of reaction intermediates by ion spectroscopy

J Roithová - Chemical Society Reviews, 2012 - pubs.rsc.org
In the last decade, we have experienced massive progress in spectroscopic methods for
mass-selected ions. The aim of this tutorial review is to present action spectroscopy as a …

Mass‐selective vibrational spectroscopy of vanadium oxide cluster ions

KR Asmis, J Sauer - Mass spectrometry reviews, 2007 - Wiley Online Library
A corner stone in the study of the size‐dependent properties of cluster ions in the gas phase
is their structural characterization. Over the last 10 years, significant progress has been in …

Hydrated metal ions in the gas phase

MK Beyer - Mass spectrometry reviews, 2007 - Wiley Online Library
Studying metal ion solvation, especially hydration, in the gas phase has developed into a
field that is dominated by a tight interaction between experiment and theory. Since the …

Vibrational manifestations of strong non-Condon effects in the H 3 O+· X 3 (X= Ar, N 2, CH 4, H2O) complexes: A possible explanation for the intensity in the “ …

AB McCoy, TL Guasco, CM Leavitt… - Physical Chemistry …, 2012 - pubs.rsc.org
The harmonic approximation provides a powerful approach for interpreting vibrational
spectra. In this treatment, the energy and intensity of the 3N− 6 normal modes are calculated …

Solvation Dynamics in Ni+(H2O)n Clusters Probed with Infrared Spectroscopy

RS Walters, ED Pillai, MA Duncan - Journal of the American …, 2005 - ACS Publications
Infrared photodissociation spectroscopy is reported for mass-selected Ni+ (H2O) n
complexes in the O− H stretching region up to cluster sizes of n= 25. These clusters fragment …

Carbon Dioxide Activation at Metal Centers: Evolution of Charge Transfer from Mg .+ to CO2 in [MgCO2(H2O)n].+, n=0–8

E Barwa, TF Pascher, M Ončák… - Angewandte Chemie …, 2020 - Wiley Online Library
We investigate activation of carbon dioxide by singly charged hydrated magnesium cations
Mg.+(H2O) n, through infrared multiple photon dissociation (IRMPD) spectroscopy combined …

Infrared studies of ionic clusters: The influence of Yuan T. Lee

JM Lisy - The Journal of chemical physics, 2006 - pubs.aip.org
Beginning in the mid-1980s, a number of innovative experimental studies on ionic clusters
emerged from the laboratory of Yuan T. Lee combining infrared laser spectroscopy and …

Frontiers in the infrared spectroscopy of gas phase metal ion complexes

NR Walker, RS Walters, MA Duncan - New Journal of Chemistry, 2005 - pubs.rsc.org
Studies of gas phase M+ (L) n cluster ions (where M is a metal atom and L is a ligand
molecule) assist our understanding of solvation and chemical processes that involve metal …

Gas-Phase Vibrational Spectroscopy of Microhydrated Magnesium Nitrate Ions [MgNO3(H2O)1−4]+

L Jiang, T Wende, R Bergmann, G Meijer… - Journal of the …, 2010 - ACS Publications
Infrared photodissociation spectra of buffer-gas-cooled [MgNO3 (H2O) n]+ complexes with
n= 1− 4 are measured in the O− H stretching region. The observed bands are assigned to …