Atom transfer radical polymerization: a mechanistic perspective

F Lorandi, M Fantin… - Journal of the American …, 2022‏ - ACS Publications
Since its inception, atom transfer radical polymerization (ATRP) has seen continuous
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …

Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications

N Corrigan, K Jung, G Moad, CJ Hawker… - Progress in Polymer …, 2020‏ - Elsevier
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …

Toward green atom transfer radical polymerization: current status and future challenges

S Dworakowska, F Lorandi, A Gorczyński… - Advanced …, 2022‏ - Wiley Online Library
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …

Stereodivergent atom-transfer radical cyclization by engineered cytochromes P450

Q Zhou, M Chin, Y Fu, P Liu, Y Yang - Science, 2021‏ - science.org
Naturally occurring enzymes can be a source of unnatural reactivity that can be molded by
directed evolution to generate efficient biocatalysts with valuable activities. Owing to the lack …

Light-controlled radical polymerization: mechanisms, methods, and applications

M Chen, M Zhong, JA Johnson - Chemical reviews, 2016‏ - ACS Publications
The use of light to mediate controlled radical polymerization has emerged as a powerful
strategy for rational polymer synthesis and advanced materials fabrication. This review …

Externally controlled atom transfer radical polymerization

X Pan, M Fantin, F Yuan, K Matyjaszewski - Chemical Society Reviews, 2018‏ - pubs.rsc.org
Spatial and temporal regulations of ATRP by external stimuli are presented. Various ATRP
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …

Photomediated controlled radical polymerization

X Pan, MA Tasdelen, J Laun, T Junkers, Y Yagci… - Progress in Polymer …, 2016‏ - Elsevier
Photomediated controlled radical polymerization is a versatile method to prepare, under
mild conditions, various well-defined polymers with complex architecture, such as block and …

Macromolecular engineering by atom transfer radical polymerization

K Matyjaszewski, NV Tsarevsky - Journal of the American …, 2014‏ - ACS Publications
This Perspective presents recent advances in macromolecular engineering enabled by
ATRP. They include the fundamental mechanistic and synthetic features of ATRP with …

Exploiting metalloporphyrins for selective living radical polymerization tunable over visible wavelengths

S Shanmugam, J Xu, C Boyer - Journal of the American Chemical …, 2015‏ - ACS Publications
The use of metalloporphyrins has been gaining popularity particularly in the area of
medicine concerning sensitizers for the treatment of cancer and dermatological diseases …

[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …

C Boyer, NA Corrigan, K Jung, D Nguyen… - Chemical …, 2016‏ - ACS Publications
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …