Understanding metal synergy in heterodinuclear catalysts for the copolymerization of CO2 and epoxides

AC Deacy, AFR Kilpatrick, A Regoutz, CK Williams - Nature chemistry, 2020 - nature.com
Carbon dioxide and epoxide copolymerization is an industrially relevant means to valorize
waste and improve sustainability in polymer manufacturing. Given the value of the polymer …

12-MC-4 metallacrowns as versatile tools for SMM research

P Happ, C Plenk, E Rentschler - Coordination Chemistry Reviews, 2015 - Elsevier
The outstanding chemical and structural features of 12-MC-4 metallacrowns allow for
versatile applications in magneto-chemical research. Herein, we present three novel …

Slow Magnetic Relaxation in Co(III)–Co(II) Mixed-Valence Dinuclear Complexes with a CoIIO5X (X = Cl, Br, NO3) Distorted-Octahedral Coordination Sphere

V Chandrasekhar, A Dey, AJ Mota… - Inorganic Chemistry, 2013 - ACS Publications
The reaction of the multisite coordination ligand (LH4) with CoX2· n H2O in the presence of
tetrabutylammonium hydroxide affords a series of homometallic dinuclear mixed-valence …

Ferromagnetic coupling through the end-to-end thiocyanate bridge in cobalt (II) and nickel (II) chains

J Palion-Gazda, B Machura, F Lloret… - Crystal Growth & …, 2015 - ACS Publications
The preparation, spectroscopic characterization, and X-ray crystal structure of two novel one-
dimensional compounds of formula [MII (tppz)(NCS)(μ-1, 3-NCS)] n [tppz= 2, 3, 5, 6-tetrakis …

Stimulation of Redox‐Induced Electron Transfer by Interligand Hydrogen Bonding in a Cobalt Complex with Redox‐Active Guanidine Ligand

L Lohmeyer, F Schön, E Kaifer… - Angewandte Chemie …, 2021 - Wiley Online Library
Octahedrally coordinated cobalt (II) complexes with a redox‐active bisguanidine ligand and
acac co‐ligands were synthesized and their redox chemistry analysed in detail. The N− H …

Two 2D transition metal coordination polymers based on 5-(1H-1, 2, 4-triazol-1-yl) isophthalic acid: synthesis, structure and magnetic properties

WW Cao, F Zhao, L Tian - Journal of Molecular Structure, 2023 - Elsevier
Two coordination polymers {[Co (TIA)(H 2 O) 2]· 0.25 H 2 O} n (Co-1), and {[Mn (TIA)(H 2 O)
2]· 0.5 H 2 O} n (Mn-2) were obtained solvothermally based on the exquisite combination of …

Study of the influence of the bridge on the magnetic coupling in cobalt (II) complexes

O Fabelo, L Cañadillas-Delgado, J Pasan… - Inorganic …, 2009 - ACS Publications
Two new cobalt (II) complexes of formula [Co2 (bta)(H2O) 6] n· 2 n H2O (1) and [Co
(phda)(H2O)] n· n H2O (2)[H4bta= 1, 2, 4, 5-benzenetetracarboxylic acid, H2phda= 1, 4 …

Hybrid sol–gel double metal cyanide catalysts for the copolymerisation of styrene oxide and CO 2

Y Dienes, W Leitner, MGJ Müller, WK Offermans… - Green chemistry, 2012 - pubs.rsc.org
Hybrid sol–gel catalysts of zinc hexacyanocobaltate and SiO2 were prepared by co-
precipitation of the double metal cyanide with silica. Hybrid catalysts prepared at moderately …

Unusual (μ-aqua) bis (μ-carboxylate) bridge in homometallic M (II)(M= Mn, Co and Ni) two-dimensional compounds based on the 1, 2, 3, 4-butanetetracarboxylic acid …

L Cañadillas-Delgado, O Fabelo, J Pasán… - Inorganic …, 2007 - ACS Publications
The first coordination compounds of 1, 2, 3, 4-butanetetracarboxylate anion (butca4-) of the
formula [M2 (butca)(H2O) 5] n⊙ 2 n H2O [M= Mn (II)(1), Co (II)(2), and Ni (II)(3)] were …

New type of single chain magnet: pseudo-one-dimensional chain of high-spin Co (II) exhibiting ferromagnetic intrachain interactions

V Tangoulis, M Lalia-Kantouri, M Gdaniec… - Inorganic …, 2013 - ACS Publications
Two new six-coordinated high-spin Co (II) complexes have been synthesized through the
reactions of Co (II) salts with dipyridylamine (dpamH) and 5-nitro-salicylaldehyde (5-NO2 …