A hybrid steric ligand modification strategy promotes propylene (co) polymerization

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Accessing Functionalized Ultra‐High Molecular Weight Poly (α‐olefin) s via Hafnium‐Mediated Highly Isospecific Copolymerization

G Zhou, H Mu, Z Jian - Macromolecular Rapid Communications, 2024 - Wiley Online Library
Inspired by the favorable impact of heteroatom‐containing groups in phenoxy‐imine titanium
and late transition metal catalysts, a series of novel pyridylamido hafnium catalysts …
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Direct synthesis of poly (α-olefin) thermoplastic elastomers via controlled chain straightening using bulky α-diimine palladium complexes

H Wang, Q Cai, S Dai - Polymer Chemistry, 2024 - pubs.rsc.org
Thermoplastic elastomers (TPEs) are considered as the third generation of rubber. How to
generate TPEs using one-step homopolymerization of α-olefin is important for polymer …
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