Oxide–and silicate–water interfaces and their roles in technology and the environment

JL Bañuelos, E Borguet, GE Brown Jr… - Chemical …, 2023 - ACS Publications
Interfacial reactions drive all elemental cycling on Earth and play pivotal roles in human
activities such as agriculture, water purification, energy production and storage …

Porous materials for the recovery of rare earth elements, platinum group metals, and other valuable metals: A review

S Iftekhar, G Heidari, N Amanat, EN Zare… - Environmental …, 2022 - Springer
The demand for valuable metals such as rare earth elements and platinum group metals is
rising fast in the context of the depletion of natural resources and international conflicts …

Adsorption at nanoconfined solid–water interfaces

AG Ilgen, K Leung, LJ Criscenti… - Annual Review of …, 2023 - annualreviews.org
Reactions at solid–water interfaces play a foundational role in water treatment systems,
catalysis, and chemical separations, and in predicting chemical fate and transport in the …

Formic and acetic acid p K a values increase under nanoconfinement

I Sit, BT Fashina, AP Baldo, K Leung, VH Grassian… - RSC …, 2023 - pubs.rsc.org
Organic acids are prevalent in the environment and their acidity and the corresponding
dissociation constants can change under varying environmental conditions. The impact of …

Thin water films enable low-temperature magnesite growth under conditions relevant to geologic carbon sequestration

SN Kerisit, ST Mergelsberg, CJ Thompson… - Environmental …, 2021 - ACS Publications
Injecting supercritical CO2 (scCO2) into basalt formations for long-term storage is a
promising strategy for mitigating CO2 emissions. Mineral carbonation can result in …

Studies of Mineral Nucleation and Growth Across Multiple Scales: Review of the Current State of Research Using the Example of Barite (BaSO4)

J Weber, JN Bracco, K Yuan… - ACS Earth and Space …, 2021 - ACS Publications
Sparingly soluble sulfate minerals, particularly barite (BaSO4), present an ideal system to
understand mineral–water interfacial reactions. The model system barite has been used to …

Local Coordination Environment of Lanthanides Adsorbed onto Cr-and Zr-based Metal–Organic Frameworks

AG Ilgen, RE Sikma, DF Sava Gallis… - … Applied Materials & …, 2024 - ACS Publications
Separating individual lanthanide (Ln) elements in aqueous mixtures is challenging. Ion-
selective capture by porous materials, such as metal–organic frameworks (MOFs), is a …

Separating Hofmeister trends in Stern and diffuse layers at a charged interface

N Tetteh, S Parshotam, JM Gibbs - The Journal of Physical …, 2024 - ACS Publications
Understanding the role of pH and ions on the electrical double layer (EDL) at charged
mineral oxide/aqueous interfaces remains crucial in modeling environmental and industrial …

Hydration states of europium (III) adsorbed on silicas with nano-sized pores

K Murota, N Aoyagi, H Mei, T Saito - Applied Geochemistry, 2023 - Elsevier
The confinement in small spaces influences the complicated reaction involving water
molecules under electrostatic potentials at the solid–liquid interface. It is unclear, in …

Urea Disrupts the AOT Reverse Micelle Structure at Low Temperatures

SL Miller, NE Levinger - Langmuir, 2022 - ACS Publications
Aside from its prominent role in the excretory system, urea is also a known protein
denaturant. Here, we characterize urea as it behaves in confined spaces of AOT (sodium bis …