N-heterocyclic carbene complexes of copper, nickel, and cobalt

AA Danopoulos, T Simler, P Braunstein - Chemical reviews, 2019‏ - ACS Publications
The emergence of N-heterocyclic carbenes as ligands across the Periodic Table had an
impact on various aspects of the coordination, organometallic, and catalytic chemistry of the …

Transition-metal-catalyzed Suzuki–Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts

FS Han - Chemical Society Reviews, 2013‏ - pubs.rsc.org
In the transition-metal-catalyzed cross-coupling reactions, the use of the first row transition
metals as catalysts is much more appealing than the precious metals owing to the apparent …

N-heterocyclic carbenes in late transition metal catalysis

S Diez-Gonzalez, N Marion, SP Nolan - Chemical Reviews, 2009‏ - ACS Publications
N-Heterocyclic carbenes (NHCs) are cyclic carbenes bearing at least one R-amino
substituent. 1 The most common subclasses of NHCs are represented in Chart 1. Early work …

Iridium and ruthenium complexes with chelating N-heterocyclic carbenes: efficient catalysts for transfer hydrogenation, β-alkylation of alcohols, and N-alkylation of …

D Gnanamgari, ELO Sauer, ND Schley, C Butler… - …, 2009‏ - ACS Publications
Air-stable Ir and Ru complexes of a chelating pyrimidine-functionalized N-heterocyclic
carbene were synthesized. The complexes were characterized by NMR spectroscopy and …

Facile synthesis of highly stable gold nanoparticles and their unexpected excellent catalytic activity for Suzuki− Miyaura cross-coupling reaction in water

J Han, Y Liu, R Guo - Journal of the American Chemical Society, 2009‏ - ACS Publications
We have demonstrated that poly (2-aminothiophenol)-stablized gold nanoparticles with
proper gold size and polymer thickness are active catalysts for Suzuki− Miyaura cross …

Donor‐functionalised n‐heterocyclic carbene complexes of Group 9 and 10 metals in catalysis: Trends and directions

AT Normand, KJ Cavell - European Journal of Inorganic …, 2008‏ - Wiley Online Library
This review focuses on the latest advances in homogeneous catalysis with donor‐
functionalised (donor= C, N, O, S or P) N‐heterocyclic carbene complexes of group 9 and 10 …

Nickel N-heterocyclic carbene-catalyzed C–C bond formation: Reactions and mechanistic aspects

M Henrion, V Ritleng, MJ Chetcuti - ACS Catalysis, 2015‏ - ACS Publications
The chemistry of nickel N-heterocyclic carbene complexes is a research area that has
blossomed over the last 10 years, and a large number of new complexes with a variety of …

Nickel N-heterocyclic carbene complexes and their utility in homogeneous catalysis

AP Prakasham, P Ghosh - Inorganica Chimica Acta, 2015‏ - Elsevier
An emerging area of the nickel N-heterocyclic carbene (NHC) complexes and their
applications in homogeneous catalysis is highlighted in the review. The review paints a …

Rhodium (I) complexes with hemilabile N-heterocyclic carbenes: Efficient alkyne hydrosilylation catalysts

MV Jiménez, JJ Pérez-Torrente, MI Bartolomé… - …, 2008‏ - ACS Publications
A series of alkylammonium-imidazolium chloride salts [RImH (CH2) n NMe2] Cl· HCl (R=
Me, t-Bu, Mes; n= 2, 3) have been prepared by alkylation of 1-substituted imidazole …

Ruthenium (II) picolyl-NHC complexes: synthesis, characterization, and catalytic activity in amine N-alkylation and transfer hydrogenation reactions

FE Fernandez, MC Puerta, P Valerga - Organometallics, 2012‏ - ACS Publications
Ruthenium (II) p-cymene complexes with picolyl-functionalized N-heterocyclic carbenes [(η6-
p-cymene) Ru (L)(Cl)][PF6](L= 3-methyl-1-(2-picolyl) imidazol-2-ylidene (1a), 3-isopropyl-1 …