Synthesis and catalytic properties of metal nanoparticles: Size, shape, support, composition, and oxidation state effects

BR Cuenya - Thin Solid Films, 2010 - Elsevier
Exciting new opportunities are emerging in the field of catalysis based on nanotechnology
approaches. A new understanding and mastery of catalysis could have broad societal …

Iron oxide surfaces

GS Parkinson - Surface Science Reports, 2016 - Elsevier
The current status of knowledge regarding the surfaces of the iron oxides, magnetite (Fe 3 O
4), maghemite (γ-Fe 2 O 3), haematite (α-Fe 2 O 3), and wüstite (Fe 1− x O) is reviewed. The …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al2O3 Catalysts Induced by Strong Metal–Support Interactions

T Lunkenbein, J Schumann, M Behrens… - Angewandte …, 2015 - Wiley Online Library
Abstract In industrially relevant Cu/ZnO/Al2O3 catalysts for methanol synthesis, the strong
metal support interaction between Cu and ZnO is known to play a key role. Here we report a …

Interface-confined ferrous centers for catalytic oxidation

Q Fu, WX Li, Y Yao, H Liu, HY Su, D Ma, XK Gu… - science, 2010 - science.org
Coordinatively unsaturated ferrous (CUF) sites confined in nanosized matrices are active
centers in a wide range of enzyme and homogeneous catalytic reactions. Preparation of the …

CO oxidation as a prototypical reaction for heterogeneous processes

HJ Freund, G Meijer, M Scheffler… - Angewandte Chemie …, 2011 - Wiley Online Library
CO oxidation, although seemingly a simple chemical reaction, provides us with a panacea
that reveals the richness and beauty of heterogeneous catalysis. The Fritz Haber Institute is …

Approaches for understanding and controlling interfacial effects in oxide-supported metal catalysts

I Ro, J Resasco, P Christopher - ACS Catalysis, 2018 - ACS Publications
Heterogeneous supported metal catalysts are critical for a wide range of chemical
conversion technologies. While the fundamental properties of extended metal surfaces are …

Tuning/exploiting strong metal-support interaction (SMSI) in heterogeneous catalysis

CJ Pan, MC Tsai, WN Su, J Rick, NG Akalework… - Journal of the Taiwan …, 2017 - Elsevier
Interactions between metals and supports are of fundamental interest in heterogeneous
catalysis. The electronic, geometric and bifunctional effects originating from Strong Metal …

Theoretical heterogeneous catalysis: scaling relationships and computational catalyst design

J Greeley - Annual review of chemical and biomolecular …, 2016 - annualreviews.org
Scaling relationships are theoretical constructs that relate the binding energies of a wide
variety of catalytic intermediates across a range of catalyst surfaces. Such relationships are …

Nanocatalysis: size-and shape-dependent chemisorption and catalytic reactivity

BR Cuenya, F Behafarid - Surface Science Reports, 2015 - Elsevier
In recent years, the field of catalysis has experienced an astonishing transformation, driven
in part by more demanding environmental standards and critical societal and industrial …