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Absolute band-edge energies are over-emphasized in the design of photoelectrochemical materials
The absolute band-edge potentials of semiconductors and their positions relative to solution
redox potentials are often invoked as design principles for photoelectrochemical devices …
redox potentials are often invoked as design principles for photoelectrochemical devices …
Photoelectrochemical CO2 Reduction to CO Enabled by a Molecular Catalyst Attached to High-Surface-Area Porous Silicon
X Jia, E Stewart-Jones… - Journal of the …, 2024 - ACS Publications
A high-surface-area p-type porous Si photocathode containing a covalently immobilized
molecular Re catalyst is highly selective for the photoelectrochemical conversion of CO2 to …
molecular Re catalyst is highly selective for the photoelectrochemical conversion of CO2 to …
Electrochemical impedance of well-passivated semiconductors reveals bandgaps, Fermi levels, and interfacial density of states
CD Hallock, MJ Rose - Journal of the American Chemical Society, 2024 - ACS Publications
For well-passivated semiconductor materials, the density of states (DOS) at the band edge
determines the concentration of electrons (or holes) available to participate in …
determines the concentration of electrons (or holes) available to participate in …
Insights into the Interfacial Charge Transfer Dynamics in Semiconductor–Molecular Catalyst Assemblies for Photo–Induced CO2 Reduction
This mini–review summarises examples of photo and photoelectrochemical CO2 reduction
reactions (CO2RR) using semiconductor–molecular catalyst–based hybrid assemblies in …
reactions (CO2RR) using semiconductor–molecular catalyst–based hybrid assemblies in …
Methyl Termination of p-Type Silicon Enables Selective Photoelectrochemical CO2 Reduction by a Molecular Ruthenium Catalyst
GP Bein, MA Stewart, EA Assaf, SJ Tereniak… - ACS Energy …, 2024 - ACS Publications
Methyl-terminated p-type silicon photoelectrodes selectively drive CO2 reduction by a
homogeneous [Ru (tpy)(Mebim-py)(NCCH3)] 2+ catalyst (tpy= 2, 2′: 6′, 2 ″-terpyridine …
homogeneous [Ru (tpy)(Mebim-py)(NCCH3)] 2+ catalyst (tpy= 2, 2′: 6′, 2 ″-terpyridine …
Catalytic Reduction of Carbon Monoxide to Liquid Fuels with Recyclable Hydride Donors
Solar light absorption and catalysis are physically separated processes in natural
photosynthesis. 1 Natural cofactors, such as nicotinamide adenine dinucleotides (NADH) …
photosynthesis. 1 Natural cofactors, such as nicotinamide adenine dinucleotides (NADH) …
Covalent Functionalization of Silicon with Plasma-Grown “Fuzzy” Graphene: Robust Aqueous Photoelectrodes for CO2 Reduction by Molecular Catalysts
Carbon electrodes are ideal for electrochemistry with molecular catalysts, exhibiting facile
charge transfer and good stability. Yet for solar-driven catalysis with semiconductor light …
charge transfer and good stability. Yet for solar-driven catalysis with semiconductor light …
Mild-Annealed Molecular Layer Deposition (MLD) Tincone Thin Film as Photoelectrochemically Stable and Efficient Electron Transport Layer for Si Photocathodes
Metalcone thin films, composed of inorganic–organic hybrids, are synthesized using
molecular layer deposition (MLD) through reactions between organometallic precursors (eg …
molecular layer deposition (MLD) through reactions between organometallic precursors (eg …
Electrochemical Characterization of Electrode Devices: Towards Enhanced Stability in Energy Storage and Photoelectrochemical Catalysis Applications
AM Jordan - 2023 - search.proquest.com
To avoid further escalation of the climate crisis, current alternative energy technologies
require immediate improvements to curb our reliance on fossil fuels. Renewable energy …
require immediate improvements to curb our reliance on fossil fuels. Renewable energy …