Dynamic molecular crystals with switchable physical properties

O Sato - Nature chemistry, 2016 - nature.com
The development of molecular materials whose physical properties can be controlled by
external stimuli—such as light, electric field, temperature, and pressure—has recently …

Molecular spin crossover phenomenon: recent achievements and prospects

A Bousseksou, G Molnár, L Salmon… - Chemical Society …, 2011 - pubs.rsc.org
Recently we assisted a strong renewed interest in the fascinating field of molecular spin
crossover complexes by (1) the emergence of nanosized spin crossover materials through …

Playing with organic radicals as building blocks for functional molecular materials

I Ratera, J Veciana - Chemical Society Reviews, 2012 - pubs.rsc.org
The literature has shown numerous contributions on the synthesis and physicochemical
properties of persistent organic radicals but there are a lesser number of reports about their …

Valence tautomerism in metal complexes: Stimulated and reversible intramolecular electron transfer between metal centers and organic ligands

T Tezgerevska, KG Alley, C Boskovic - Coordination Chemistry Reviews, 2014 - Elsevier
The defining characteristic of a valence tautomeric (VT) transition in a metal complex with a
redox-active organic ligand is a stimulated intramolecular electron transfer between metal …

Tautomerism unveils a self-inhibition mechanism of crystallization

W Tang, T Yang, CA Morales-Rivera, X Geng… - Nature …, 2023 - nature.com
Modifiers are commonly used in natural, biological, and synthetic crystallization to tailor the
growth of diverse materials. Here, we identify tautomers as a new class of modifiers where …

Inorganic–organic hybrid photochromic materials

MS Wang, G Xu, ZJ Zhang, GC Guo - Chemical Communications, 2010 - pubs.rsc.org
The distinct synergetic characteristics between each component in inorganic–organic
hybrids offer various possibilities to obtain new “smart”, high performing materials. Growing …

Predicting valence tautomerism in diverse cobalt–dioxolene complexes: elucidation of the role of ligands and solvent

FZM Zahir, MA Hay, JT Janetzki, RW Gable… - Chemical …, 2024 - pubs.rsc.org
The ability of molecular switches to reversibly interconvert between different forms promises
potential applications at the scale of single molecules up to bulk materials. One type of …

Light-Controlled Multiconfigurational Conductance Switching in a Single 1D Metal–Organic Wire

A Cahlik, M Ondracek, C Wackerlin, AP Solé, O Siri… - ACS …, 2024 - ACS Publications
Precise control of multiple spin states on the atomic scale presents a promising avenue for
designing and realizing magnetic switches. Despite substantial progress in recent decades …