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Dynamic molecular crystals with switchable physical properties
O Sato - Nature chemistry, 2016 - nature.com
The development of molecular materials whose physical properties can be controlled by
external stimuli—such as light, electric field, temperature, and pressure—has recently …
external stimuli—such as light, electric field, temperature, and pressure—has recently …
Molecular spin crossover phenomenon: recent achievements and prospects
Recently we assisted a strong renewed interest in the fascinating field of molecular spin
crossover complexes by (1) the emergence of nanosized spin crossover materials through …
crossover complexes by (1) the emergence of nanosized spin crossover materials through …
Playing with organic radicals as building blocks for functional molecular materials
The literature has shown numerous contributions on the synthesis and physicochemical
properties of persistent organic radicals but there are a lesser number of reports about their …
properties of persistent organic radicals but there are a lesser number of reports about their …
Valence tautomerism in metal complexes: Stimulated and reversible intramolecular electron transfer between metal centers and organic ligands
T Tezgerevska, KG Alley, C Boskovic - Coordination Chemistry Reviews, 2014 - Elsevier
The defining characteristic of a valence tautomeric (VT) transition in a metal complex with a
redox-active organic ligand is a stimulated intramolecular electron transfer between metal …
redox-active organic ligand is a stimulated intramolecular electron transfer between metal …
Tautomerism unveils a self-inhibition mechanism of crystallization
Modifiers are commonly used in natural, biological, and synthetic crystallization to tailor the
growth of diverse materials. Here, we identify tautomers as a new class of modifiers where …
growth of diverse materials. Here, we identify tautomers as a new class of modifiers where …
Inorganic–organic hybrid photochromic materials
MS Wang, G Xu, ZJ Zhang, GC Guo - Chemical Communications, 2010 - pubs.rsc.org
The distinct synergetic characteristics between each component in inorganic–organic
hybrids offer various possibilities to obtain new “smart”, high performing materials. Growing …
hybrids offer various possibilities to obtain new “smart”, high performing materials. Growing …
Predicting valence tautomerism in diverse cobalt–dioxolene complexes: elucidation of the role of ligands and solvent
The ability of molecular switches to reversibly interconvert between different forms promises
potential applications at the scale of single molecules up to bulk materials. One type of …
potential applications at the scale of single molecules up to bulk materials. One type of …
Light-Controlled Multiconfigurational Conductance Switching in a Single 1D Metal–Organic Wire
Precise control of multiple spin states on the atomic scale presents a promising avenue for
designing and realizing magnetic switches. Despite substantial progress in recent decades …
designing and realizing magnetic switches. Despite substantial progress in recent decades …