Sulfonic and phosphonic porous solids as proton conductors

SS Liu, QQ Liu, SZ Huang, C Zhang, XY Dong… - Coordination Chemistry …, 2022 - Elsevier
Over the past decades, solid-state ordered porous materials (SSOPMs), including newly-
emerging metal-organic frameworks (MOFs), metal-organic polyhedra (MOPs), covalent …

Photoreactive crystals exhibiting [2+ 2] photocycloaddition reaction and dynamic effects

BB Rath, JJ Vittal - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Conducting a reaction in the solid state eliminates the usage of solvents. If such
reactions are conducted in a single-crystal to single-crystal (SCSC) fashion, then structural …

Elastic organic semiconducting single crystals for durable all-flexible field-effect transistors: insights into the bending mechanism

R Samanta, S Das, S Mondal, T Alkhidir… - Chemical …, 2023 - pubs.rsc.org
Although many examples of mechanically flexible crystals are currently known, their utility in
all-flexible devices is not yet adequately demonstrated, despite their immense potential for …

Phase Transition‐Promoted Rapid Photomechanical Motions of Single Crystals of a Triene Coordination Polymer

C Cao, XR Xue, QY Li, MJ Zhang… - Angewandte Chemie …, 2023 - Wiley Online Library
Molecular crystals with the ability to transform light energy into macroscopic mechanical
motions are a promising class of materials with potential applications in actuating and …

Mechanical bending and modulation of photoactuation properties in a one-dimensional Pb (II) coordination polymer

BB Rath, JJ Vittal - Chemistry of Materials, 2021 - ACS Publications
With emerging research on stimuli-responsive materials, dynamic crystals are at the forefront
of investigation. However, research on the mechanical properties of coordination polymers …

Multistimuli-responsive dynamic effects in a one-dimensional coordination polymer

BB Rath, M Gupta, JJ Vittal - Chemistry of Materials, 2021 - ACS Publications
The development of multistimuli-receptive actuators demands a rational combination of
suitable functionalities. Achieving such actuating properties in a single crystalline material is …

Exceptionally high work density of a ferroelectric dynamic organic crystal around room temperature

DP Karothu, R Ferreira, G Dushaq, E Ahmed… - Nature …, 2022 - nature.com
Dynamic organic crystals are rapidly gaining traction as a new class of smart materials for
energy conversion, however, they are only capable of very small strokes (< 12%) and most …

Shape‐Memory Effect Enabled by Ligand Substitution and CO2 Affinity in a Flexible SIFSIX Coordination Network

BQ Song, M Shivanna, MY Gao… - Angewandte Chemie …, 2023 - Wiley Online Library
We report that linker ligand substitution involving just one atom induces a shape‐memory
effect in a flexible coordination network. Specifically, whereas SIFSIX‐23‐Cu,[Cu (SiF6)(L) 2] …

Stress‐Induced Inversion of Linear Dichroism by 4, 4′‐Bipyridine Rotation in a Superelastic Organic Single Crystal

YX Li, ZK Liu, J Cao, J Tao… - Angewandte Chemie …, 2023 - Wiley Online Library
The molecular crystals that manifest unusual mechanical properties have attracted growing
attention. Herein, we prepared an organic single crystal that shows bidirectional superelastic …

Two-dimensional anisotropic flexibility of mechanically responsive crystalline cadmium (II) coordination polymers

M Pisačić, I Kodrin, A Trninić, M Đaković - Chemistry of materials, 2022 - ACS Publications
Crystals of a family of six one-dimensional (1D) coordination polymers of cadmium (II) with
cyanopyridines [[CdX2L2] n, where X= Cl, Br, or I and L= 3-cyanopyridine (3-CNpy) or 4 …