Advanced porous adsorbents for radionuclides elimination

M Hao, Y Liu, W Wu, S Wang, X Yang, Z Chen, Z Tang… - EnergyChem, 2023 - Elsevier
With the rapid development of nuclear industry, effective management of nuclear waste and
oversight of nuclear fuel cycle are critical. Radionuclides such as uranium (U), plutonium …

Covalent organic frameworks for photocatalysis: Synthesis, structural features, fundamentals and performance

YN Gong, X Guan, HL Jiang - Coordination Chemistry Reviews, 2023 - Elsevier
Covalent organic frameworks (COFs) are a new class of crystalline porous materials
obtained from covalently attached organic building units. By virtue of the unique …

Tuning excited state electronic structure and charge transport in covalent organic frameworks for enhanced photocatalytic performance

Z Chen, J Wang, M Hao, Y **e, X Liu, H Yang… - Nature …, 2023 - nature.com
Covalent organic frameworks (COFs) represent an emerging class of organic photocatalysts.
However, their complicated structures lead to indeterminacy about photocatalytic active sites …

Computation-based regulation of excitonic effects in donor-acceptor covalent organic frameworks for enhanced photocatalysis

Y Qian, Y Han, X Zhang, G Yang, G Zhang… - Nature …, 2023 - nature.com
The strong excitonic effects widely exist in polymer-semiconductors and the large exciton
binding energy (E b) seriously limits their photocatalysis. Herein, density functional theory …

Three-component donor− π–acceptor covalent–organic frameworks for boosting photocatalytic hydrogen evolution

Z Li, T Deng, S Ma, Z Zhang, G Wu… - Journal of the …, 2023 - ACS Publications
Two-dimensional covalent–organic frameworks (2D COFs) have recently emerged as great
prospects for their applications as new photocatalytic platforms in solar-to-hydrogen …

Tuning local charge distribution in multicomponent covalent organic frameworks for dramatically enhanced photocatalytic uranium extraction

H Yang, M Hao, Y **e, X Liu, Y Liu… - Angewandte Chemie …, 2023 - Wiley Online Library
Optimizing the electronic structure of covalent organic framework (COF) photocatalysts is
essential for maximizing photocatalytic activity. Herein, we report an isoreticular family of …

Linking oxidative and reductive clusters to prepare crystalline porous catalysts for photocatalytic CO2 reduction with H2O

J Zhou, J Li, L Kan, L Zhang, Q Huang, Y Yan… - Nature …, 2022 - nature.com
Mimicking natural photosynthesis to convert CO2 with H2O into value-added fuels achieving
overall reaction is a promising way to reduce the atmospheric CO2 level. Casting the …

Covalent organic frameworks for energy conversion in photocatalysis

T He, Y Zhao - Angewandte Chemie International Edition, 2023 - Wiley Online Library
Intensifying energy crises and severe environmental issues have led to the discovery of
renewable energy sources, sustainable energy conversion, and storage technologies …

Thiophene‐Containing Covalent Organic Frameworks for Overall Photocatalytic H2O2 Synthesis in Water and Seawater

JY Yue, LP Song, YF Fan, ZX Pan… - Angewandte Chemie …, 2023 - Wiley Online Library
H2O2 is a significant chemical widely utilized in the environmental and industrial fields, with
growing global demand. Without sacrificial agents, simultaneous photocatalyzed H2O2 …

Covalent organic frameworks towards photocatalytic applications: Design principles, achievements, and opportunities

S Liu, M Wang, Y He, Q Cheng, T Qian… - Coordination Chemistry …, 2023 - Elsevier
As a subclass of porous framework materials, covalent organic frameworks (COFs) feature
permanent porosity, long-range order, and rigid backbones, and offer an important material …