Controlled photoinduced generation of “visual” partially and fully charge separated states in viologen analogues

L Liu, Q Liu, R Li, MS Wang… - Journal of the American …, 2021 - ACS Publications
Charge-separated states with a lifetime scale of seconds or longer not only favor studies
using various steady-state analysis techniques but are important for light-energy conversion …

Nonplanar butterfly‐shaped π‐expanded pyrrolopyrroles

M Krzeszewski, T Kodama, EM Espinoza… - … A European Journal, 2016 - Wiley Online Library
Large aza‐analogues of curved polycyclic aromatic hydrocarbons with a double‐helicene
structure present unique features for molecular photonics. We present the preparation and …

Photobehavior and nonlinear optical properties of push–pull, symmetrical, and highly fluorescent benzothiadiazole derivatives

F Ricci, F Elisei, P Foggi, A Marrocchi… - The Journal of …, 2016 - ACS Publications
Three quadrupolar D− π–A− π–D compounds, bearing alkoxy phenyls as mild electron
donors and a benzothiadiazole (A), two benzothiadiazoles (B), or a benzothiadiazole linked …

Nonlinear optical properties of a new panchromatic series of water-soluble bicationic push-pull fluorophores

L Mencaroni, C Bonaccorso, V Botti, B Carlotti… - Dyes and …, 2021 - Elsevier
Six water-soluble bications, characterized by a symmetric A+-π-D-π-A+ structure, were
synthesized and comprehensively studied for their absorption and fluorescence properties …

Rational design of near‐infrared absorbing organic dyes: Controlling the HOMO–LUMO gap using quantitative molecular orbital theory

AK Narsaria, J Poater… - Journal of …, 2018 - Wiley Online Library
Principles are presented for the design of functional near‐infrared (NIR) organic dye
molecules composed of simple donor (D), spacer (π), and acceptor (A) building blocks in a …

Experimental evidence of dual emission in a negatively solvatochromic push–pull pyridinium derivative

B Carlotti, A Cesaretti, CG Fortuna… - Physical Chemistry …, 2015 - pubs.rsc.org
We report here experimental evidence of dual emission in a cationic push–pull system
(bearing a methyl pyridinium group as an electron acceptor and a diphenylamino group as …

Multiple Intramolecular Charge Transfers in Multimodular Donor–Acceptor Chromophores with Large Two-Photon Absorption

Y Rout, A Cesaretti, E Ferraguzzi… - The Journal of …, 2020 - ACS Publications
New multimodular donor–acceptor chromophores combining phenothiazine (D′),
benzothiadiazole (A), and diphenylamine/carbazole (D) units in complex configurations (D …

Zinc Chloride‐Promoted Coupling Reaction between Calcium Carbide and Aryl Chlorides

T **g, N Liu, C Xu, Q Bu - European Journal of Organic …, 2022 - Wiley Online Library
The direct synthesis of diarylethynes from less‐reactive aryl chlorides and calcium carbide
was accomplished by palladium catalysis. The coupling reaction is provided with broad …

Presence of two emissive minima in the lowest excited state of a push–pull cationic dye unequivocally proved by femtosecond up-conversion spectroscopy and …

E Benassi, B Carlotti, M Segado… - The Journal of …, 2015 - ACS Publications
The long-standing controversy about the presence of two different emissive minima in the
lowest excited state of the cationic push–pull dye o-(p-dimethylamino-styryl) …

Unravelling the solvent polarity effect on the excited state intramolecular proton transfer mechanism of the 1-and 2-salicylideneanthrylamine. A TD-DFT case study

WA Muriel, R Morales-Cueto… - Physical Chemistry …, 2019 - pubs.rsc.org
Time dependent density functional theory has been used to investigate the photochemical
and photophysical processes involved in the excited states relaxation of 1-and 2 …