Structure, function, and mechanism of the nickel metalloenzymes, CO dehydrogenase, and acetyl-CoA synthase

M Can, FA Armstrong, SW Ragsdale - Chemical reviews, 2014 - ACS Publications
1.1. Research on Catalytic Reactions Involving CO and CO2: Relationship to Energy, the
Environment, Biogeochemistry, Toxicology, Health, and Technology The major …

Multiplet effects in X-ray spectroscopy

F De Groot - Coordination Chemistry Reviews, 2005 - Elsevier
This review gives an overview of the presence of multiplet effects in X-ray spectroscopy, with
an emphasis on X-ray absorption studies on 3d transition metal ions in inorganic oxides and …

Identifying Dense NiSe2/CoSe2 Heterointerfaces Coupled with Surface High‐Valence Bimetallic Sites for Synergistically Enhanced Oxygen Electrocatalysis

X Zheng, X Han, Y Cao, Y Zhang… - Advanced …, 2020 - Wiley Online Library
Constructing heterostructures with abundant interfaces is essential for integrating the
multiple functionalities in single entities. Herein, the synthesis of NiSe2/CoSe2 …

Theory-driven design of high-valence metal sites for water oxidation confirmed using in situ soft X-ray absorption

X Zheng, B Zhang, P De Luna, Y Liang, R Comin… - Nature …, 2018 - nature.com
The efficiency with which renewable fuels and feedstocks are synthesized from electrical
sources is limited at present by the sluggish oxygen evolution reaction (OER) in pH-neutral …

X-ray absorption spectroscopy to analyze nuclear geometry and electronic structure of biological metal centers—potential and questions examined with special focus …

H Dau, P Liebisch, M Haumann - Analytical and bioanalytical chemistry, 2003 - Springer
X-ray absorption spectroscopy (XAS) has become a prominent tool for the element-specific
analysis of transition metals at the catalytic center of metalloenzymes. In the present study …

Life on carbon monoxide: X-ray structure of Rhodospirillum rubrum Ni-Fe-S carbon monoxide dehydrogenase

CL Drennan, J Heo, MD Sintchak… - Proceedings of the …, 2001 - National Acad Sciences
A crystal structure of the anaerobic Ni-Fe-S carbon monoxide dehydrogenase (CODH) from
Rhodospirillum rubrum has been determined to 2.8-Å resolution. The CODH family, for …

The Ni-containing carbon monoxide dehydrogenase family: light at the end of the tunnel?

PA Lindahl - Biochemistry, 2002 - ACS Publications
Metalloenzymes seem to “come of age” when their structures are known at atomic
resolution, spectroscopic and catalytic properties are basically understood, and genetic …

X-ray magnetic circular dichroism—a high energy probe of magnetic properties

T Funk, A Deb, SJ George, H Wang… - Coordination Chemistry …, 2005 - Elsevier
X-ray magnetic circular dichroism (XMCD) spectroscopy is a powerful emerging technique
that measures difference in absorption of left-and right-circularly polarized X-rays by a …

Nickel L-edge soft X-ray spectroscopy of nickel− iron hydrogenases and model compounds evidence for high-spin nickel (II) in the active enzyme

H Wang, CY Ralston, DS Patil, RM Jones… - Journal of the …, 2000 - ACS Publications
L-edge X-ray absorption spectroscopy has been used to study, under a variety of conditions,
the electronic structure of Ni in the Ni− Fe hydrogenases from Desulfovibrio gigas …

Electronic Structure of Four-Coordinate C3v Nickel(II) Scorpionate Complexes:  Investigation by High-Frequency and -Field Electron Paramagnetic Resonance …

PJ Desrochers, J Telser, SA Zvyagin… - Inorganic …, 2006 - ACS Publications
A series of complexes of formula Tp* NiX, where Tp*-= hydrotris (3, 5-dimethylpyrazole)
borate and X= Cl, Br, I, has been characterized by electronic absorption spectroscopy in the …