Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
Chiroptical properties in thin films of π-conjugated systems
Chiral π-conjugated molecules provide new materials with outstanding features for current
and perspective applications, especially in the field of optoelectronic devices. In thin films …
and perspective applications, especially in the field of optoelectronic devices. In thin films …
Supramolecular helical systems: helical assemblies of small molecules, foldamers, and polymers with chiral amplification and their functions
E Yashima, N Ousaka, D Taura, K Shimomura… - Chemical …, 2016 - ACS Publications
In this review, we describe the recent advances in supramolecular helical assemblies
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …
Supramolecular chiral polymeric aggregates: Construction and applications
Inspired by the mystery of natural homochirality, the design and construction of artificial
chiral systems with special functions including mechanics, chiroptical devices, and chiral …
chiral systems with special functions including mechanics, chiroptical devices, and chiral …
Solute–solvent interactions in modern physical organic chemistry: Supramolecular polymers as a muse
MFJ Mabesoone, ARA Palmans… - Journal of the American …, 2020 - ACS Publications
Interactions between solvents and solutes are a cornerstone of physical organic chemistry
and have been the subject of investigations over the last century. In recent years, a renewed …
and have been the subject of investigations over the last century. In recent years, a renewed …
[HTML][HTML] Stimuli-responsive synthetic helical polymers
M Lago-Silva, M Fernández-Míguez… - Chemical Society …, 2024 - pubs.rsc.org
Synthetic dynamic helical polymers (supramolecular and covalent) and foldamers share the
helix as a structural motif. Although the materials are different, these systems also share …
helix as a structural motif. Although the materials are different, these systems also share …
Chloride capture using a C–H hydrogen-bonding cage
Tight binding and high selectivity are hallmarks of biomolecular recognition. Achieving these
behaviors with synthetic receptors has usually been associated with OH and NH hydrogen …
behaviors with synthetic receptors has usually been associated with OH and NH hydrogen …
Circularly polarized luminescence polymers: From design to applications
S Yang, S Zhang, F Hu, J Han, F Li - Coordination Chemistry Reviews, 2023 - Elsevier
Circularly polarized luminescence (CPL) materials have received extensive interest due to
their unique optical activity. An increasing number of research endeavors were focused on …
their unique optical activity. An increasing number of research endeavors were focused on …
Helical polymers: synthesis, structures, and functions
The helix is the central structural motif in biological macromolecules, such as DNA and
proteins, and is also the ubiquitous object in nature from microscopic to macroscopic points …
proteins, and is also the ubiquitous object in nature from microscopic to macroscopic points …
Acceleration of global warming due to carbon-cycle feedbacks in a coupled climate model
The continued increase in the atmospheric concentration of carbon dioxide due to
anthropogenic emissions is predicted to lead to significant changes in climate. About half of …
anthropogenic emissions is predicted to lead to significant changes in climate. About half of …