Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers

P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Chiroptical properties in thin films of π-conjugated systems

G Albano, G Pescitelli, L Di Bari - Chemical reviews, 2020 - ACS Publications
Chiral π-conjugated molecules provide new materials with outstanding features for current
and perspective applications, especially in the field of optoelectronic devices. In thin films …

Supramolecular helical systems: helical assemblies of small molecules, foldamers, and polymers with chiral amplification and their functions

E Yashima, N Ousaka, D Taura, K Shimomura… - Chemical …, 2016 - ACS Publications
In this review, we describe the recent advances in supramolecular helical assemblies
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …

Supramolecular chiral polymeric aggregates: Construction and applications

G Zhang, X Cheng, Y Wang, W Zhang - Aggregate, 2023 - Wiley Online Library
Inspired by the mystery of natural homochirality, the design and construction of artificial
chiral systems with special functions including mechanics, chiroptical devices, and chiral …

Solute–solvent interactions in modern physical organic chemistry: Supramolecular polymers as a muse

MFJ Mabesoone, ARA Palmans… - Journal of the American …, 2020 - ACS Publications
Interactions between solvents and solutes are a cornerstone of physical organic chemistry
and have been the subject of investigations over the last century. In recent years, a renewed …

[HTML][HTML] Stimuli-responsive synthetic helical polymers

M Lago-Silva, M Fernández-Míguez… - Chemical Society …, 2024 - pubs.rsc.org
Synthetic dynamic helical polymers (supramolecular and covalent) and foldamers share the
helix as a structural motif. Although the materials are different, these systems also share …

Chloride capture using a C–H hydrogen-bonding cage

Y Liu, W Zhao, CH Chen, AH Flood - Science, 2019 - science.org
Tight binding and high selectivity are hallmarks of biomolecular recognition. Achieving these
behaviors with synthetic receptors has usually been associated with OH and NH hydrogen …

Circularly polarized luminescence polymers: From design to applications

S Yang, S Zhang, F Hu, J Han, F Li - Coordination Chemistry Reviews, 2023 - Elsevier
Circularly polarized luminescence (CPL) materials have received extensive interest due to
their unique optical activity. An increasing number of research endeavors were focused on …

Helical polymers: synthesis, structures, and functions

E Yashima, K Maeda, H Iida, Y Furusho… - Chemical …, 2009 - ACS Publications
The helix is the central structural motif in biological macromolecules, such as DNA and
proteins, and is also the ubiquitous object in nature from microscopic to macroscopic points …

Acceleration of global warming due to carbon-cycle feedbacks in a coupled climate model

PM Cox, RA Betts, CD Jones, SA Spall, IJ Totterdell - Nature, 2000 - nature.com
The continued increase in the atmospheric concentration of carbon dioxide due to
anthropogenic emissions is predicted to lead to significant changes in climate. About half of …