1, 1, 1, 3, 3, 3-Hexafluoroisopropanol (HFIP) is a polar, strongly hydrogen bond-donating
solvent that has found numerous uses in organic synthesis due to its ability to stabilize ionic …

Photoinduced chemical transformations have received in recent years a tremendous amount
of attention, providing a plethora of opportunities to synthetic organic chemists. However …

Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …

We describe a new electrophotocatalytic strategy that harnesses the power of light and
electricity to generate an excited radical anion with a reducing potential of− 3.2 V vs SCE …

Abstract 1, 1, 1, 3, 3, 3-Hexafluoroisopropanol (HFIP) has recently become a very popular
solvent or additive with applications across the spectrum of chemistry. Analysis shows that it …

Herein, we report a conceptually novel borylation reaction proceeding via a mild
photoinduced decarboxylation of redox-activated aromatic carboxylic acids. This work …

A metal‐free radical borylation of alkyl and aryl iodides with bis (catecholato) diboron
(B2cat2) as the boron source under mild conditions is introduced. The borylation reaction is …

An efficient method for the metal‐free deaminative borylation of alkylamines, using bis
(catecholato) diboron as the boron source, to directly synthesize various alkyl potassium …

The conventional methods for preparing alkyl boronates often necessitate anhydrous and
demanding reaction conditions. Herein, a new, operationally simple decarboxylative …

Enamides, functional derivatives of enamines, play a significant role as synthetic targets.
However, the stereoselective synthesis of these molecules has posed a longstanding …