Sustainability assessment of mechanochemistry by using the twelve principles of green chemistry

KJ Ardila‐Fierro, JG Hernández - ChemSusChem, 2021 - Wiley Online Library
In recent years, mechanochemistry has been growing into a widely accepted alternative for
chemical synthesis. In addition to their efficiency and practicality, mechanochemical …

Advancing mechanochemical synthesis by combining milling with different energy sources

V Martinez, T Stolar, B Karadeniz, I Brekalo… - Nature Reviews …, 2023 - nature.com
Owing to its efficiency and unique reactivity, mechanochemical processing of bulk solids has
developed into a powerful tool for the synthesis and transformation of various classes of …

Mechanochemistry: new tools to navigate the uncharted territory of “impossible” reactions

F Cuccu, L De Luca, F Delogu, E Colacino… - …, 2022 - Wiley Online Library
Mechanochemical transformations have made chemists enter unknown territories, forcing a
different chemistry perspective. While questioning or revisiting familiar concepts belonging …

Methods for monitoring milling reactions and mechanistic studies of mechanochemistry: a primer

PA Julien, T Friščić - Crystal Growth & Design, 2022 - ACS Publications
Mechanochemistry by ball milling is garnering significant attention as an efficient and
versatile means of chemical synthesis which minimizes the need for solvents and reduces …

Wetting vs Droplet Aggregation: A Broadband Rotational Spectroscopic Study of 3‐Methylcatechol⋅⋅⋅ Water Clusters

AS Hazrah, A Insausti, J Ma, MH Al‐Jabiri… - Angewandte …, 2023 - Wiley Online Library
Two competing solvation pathways of 3‐methylcatechol (MC), an atmospherically relevant
aromatic molecule, with up to five water molecules were explored in detail by using a …

Mechanochemical methods for the transfer of electrons and exchange of ions: inorganic reactivity from nanoparticles to organometallics

BG Fiss, AJ Richard, G Douglas, M Kojic… - Chemical Society …, 2021 - pubs.rsc.org
Mechanochemistry by milling, grinding, extrusion or other types of shear and mechanical
agitation has shown novel reactivity for a wide range of reactions, not seen in traditional …

Synthesis without solvent: consequences for mechanochemical reactivity

LE Wenger, TP Hanusa - Chemical Communications, 2023 - pubs.rsc.org
Solvents are so nearly omnipresent in synthetic chemistry that a classic question for their
use has been:“What is the best solvent for this reaction?” The increasing use of …

Mechanochemical Mediated Coexistence of B← N Coordination and Hydrogen Bonding

M Guadalupe Vasquez‐Ríos… - Angewandte …, 2023 - Wiley Online Library
Mechanochemistry afforded a photoactive cocrystal via coexisting (B) O− H⋅⋅⋅ N hydrogen
bonds and B← N coordination. Specifically, solvent‐free mechanochemical ball mill grinding …

Mechanochemical transformation of planar polyarenes to curved fused-ring systems

T Yong, G Báti, F García, MC Stuparu - Nature Communications, 2021 - nature.com
The transformation of planar aromatic molecules into π-extended non-planar structures is a
challenging task and has not been realized by mechanochemistry before. Here we report …

Mechanochemical synthesis of cocrystal: From mechanism to application

Y **ao, C Wu, X Hu, K Chen, L Qi, P Cui… - Crystal Growth & …, 2023 - ACS Publications
Cocrystal engineering is gaining interest across various disciplines since it can effectively
tune the properties of solid substances via noncovalent synthesis by introducing new …