A critical review on correlating active sites, oxidative species and degradation routes with persulfate-based antibiotics oxidation
At present, numerous heterogeneous catalysts have been synthesized to activate persulfate
(PS) and produce various reactive species for antibiotic degradation from water. However …
(PS) and produce various reactive species for antibiotic degradation from water. However …
Challenges and opportunities in engineering the electronic structure of single-atom catalysts
Controlling the electronic structure of transition-metal single-atom heterogeneous catalysts
(SACs) is crucial to unlocking their full potential. The ability to do this with increasing …
(SACs) is crucial to unlocking their full potential. The ability to do this with increasing …
Insights into the activity of single-atom Fe-NC catalysts for oxygen reduction reaction
K Liu, J Fu, Y Lin, T Luo, G Ni, H Li, Z Lin… - Nature …, 2022 - nature.com
Single-atom Fe-NC catalysts has attracted widespread attentions in the oxygen reduction
reaction (ORR). However, the origin of ORR activity on Fe-NC catalysts is still unclear, which …
reaction (ORR). However, the origin of ORR activity on Fe-NC catalysts is still unclear, which …
Regulating the Spin State of FeIII Enhances the Magnetic Effect of the Molecular Catalysis Mechanism
Z Sun, L Lin, J He, D Ding, T Wang, J Li… - Journal of the …, 2022 - ACS Publications
Aqueous-phase oxygen evolution reaction (OER) is the bottleneck of water splitting. The
formation of the O–O bond involves the generation of paramagnetic oxygen molecules from …
formation of the O–O bond involves the generation of paramagnetic oxygen molecules from …
Spin selection in atomic-level chiral metal oxide for photocatalysis
The spin degree of freedom is an important and intrinsic parameter in boosting carrier
dynamics and surface reaction kinetics of photocatalysis. Here we show that chiral structure …
dynamics and surface reaction kinetics of photocatalysis. Here we show that chiral structure …
An adjacent atomic platinum site enables single‐atom iron with high oxygen reduction reaction performance
The modulation effect has been widely investigated to tune the electronic state of single‐
atomic M‐N‐C catalysts to enhance the activity of oxygen reduction reaction (ORR) …
atomic M‐N‐C catalysts to enhance the activity of oxygen reduction reaction (ORR) …
Unraveling the origin of sulfur‐doped Fe‐N‐C single‐atom catalyst for enhanced oxygen reduction activity: effect of iron spin‐state tuning
Heteroatom doped atomically dispersed Fe1‐NC catalysts have been found to show
excellent activity toward oxygen reduction reaction (ORR). However, the origin of the …
excellent activity toward oxygen reduction reaction (ORR). However, the origin of the …
Spin-state-dependent peroxymonosulfate activation of single-atom M–N moieties via a radical-free pathway
Transition metal catalysts are known to activate persulfate, but the properties that govern the
intrinsic activity of these catalysts are still unknown. Here, we developed a series of catalysts …
intrinsic activity of these catalysts are still unknown. Here, we developed a series of catalysts …
Improved electronic structure from spin-state reconstruction of a heteronuclear Fe–Co diatomic pair to boost the Fenton-like reaction
Dual-atom catalysts (DACs) are promising candidates for various catalytic reactions,
including electrocatalysis, chemical synthesis, and environmental remediation. However, the …
including electrocatalysis, chemical synthesis, and environmental remediation. However, the …
Activity and Selectivity Roadmap for C–N Electro-Coupling on MXenes
Electrochemical coupling between carbon and nitrogen species to generate high-value C–N
products, including urea, presents significant economic and environmental potentials for …
products, including urea, presents significant economic and environmental potentials for …