Charge‐shift bonding: a new and unique form of bonding

S Shaik, D Danovich, JM Galbraith, B Braïda… - Angewandte …, 2020 - Wiley Online Library
Charge‐shift bonds (CSBs) constitute a new class of bonds different than covalent/polar‐
covalent and ionic bonds. Bonding in CSBs does not arise from either the covalent or the …

Boron-containing small rings: synthesis, properties, and application prospects

UM Dzhemilev, LI Khusainova, KS Ryazanov… - Russian Chemical …, 2021 - Springer
The studies published over the last 15 years on the synthesis, physicochemical properties,
and application prospects of saturated and unsaturated three-and four-membered boron …

A facile and selective route to remarkably inert monocyclic NHC-stabilized boriranes

H Braunschweig, C Claes, A Damme… - Chemical …, 2015 - pubs.rsc.org
Herein we report a facile and selective synthetic route to monocyclic NHC-stabilized
boriranes. We have succeeded in obtaining two highly stable new boriranes through salt …

Role of Electronegativity on the Elemental Diversity in High-Entropy Alloys

RA Oshiya, B Varghese, A Datta - Journal of the American …, 2024 - ACS Publications
High-entropy alloys (HEAs) or multi-principal element alloys (MPEAs) have found extensive
applications in high-precision devices. While the increased configurational entropy for HEAs …

[HTML][HTML] An organized collection of theoretical gas-phase geometric, spectroscopic, and thermochemical data of oxygenated hydrocarbons, CxHyOz (x, y= 1, 2; z= 1–8) …

JM Simmie, J Würmel - Journal of Physical and Chemical Reference …, 2020 - pubs.aip.org
The objective of this work is to present a unified collection of structural and chemical
information on a series of neutral chemical tri-elemental species up to a molecular formula C …

Heretical thoughts about the present understanding and description of the chemical bond

G Frenking - Molecular Physics, 2023 - Taylor & Francis
Full article: Heretical thoughts about the present understanding and description of the chemical
bond* Skip to Main Content Taylor and Francis Online homepage Taylor and Francis Online …

Exploring the nature of electron-pair bonds: an energy decomposition analysis perspective

Y Zhang, X Wu, P Su, W Wu - Journal of Physics: Condensed …, 2022 - iopscience.iop.org
In this paper, the nature of electron-pair bonds is explored from an energy decomposition
perspective. The recently developed valence bond energy decomposition analysis (VB …

The Carbon–Nitrogen Bonds in Ammonium Compounds Are Charge Shift Bonds

R Gershoni‐Poranne, P Chen - Chemistry–A European …, 2017 - Wiley Online Library
A comprehensive investigation, utilizing valence‐bond‐and molecular‐orbital‐based
techniques, reveals that C− N bonds in protonated and methylated ammonium compounds …

Computational Modeling of the Feasibility of Substituted [1.1. 1] Propellane Formation from Anionic Bridgehead Bromide Precursors

KE Gates, C Herring, AT Lumpkin, RJ Maraski… - Organics, 2023 - mdpi.com
[1.1. 1] Propellane, a compound whose structure includes two saturated carbons in which all
four bonds are directed into a single hemisphere, is of theoretical interest, but has also seen …

Covalent Bonding and Charge Shift Bonds: Comment on “The Carbon–Nitrogen Bonds in Ammonium Compounds Are Charge Shift Bonds”

G Frenking - Chemistry–A European Journal, 2017 - Wiley Online Library
Abstract The paper by Gershoni‐Poranne and Chen (R. Gershoni‐Poranne, P. Chen, Chem.
Eur. J. 2017, 23, 4659) gives an incorrect definition of covalent bonding. Furthermore, the …