Coherence in Chemistry: Foundations and Frontiers

JD Schultz, JL Yuly, EA Arsenault, K Parker… - Chemical …, 2024 - ACS Publications
Coherence refers to correlations in waves. Because matter has a wave-particle nature, it is
unsurprising that coherence has deep connections with the most contemporary issues in …

Regio-and steric effects on single molecule conductance of phenanthrenes

Y Chen, M Huang, Q Zhou, Z Li, J Meng, M Pan… - Nano Letters, 2021 - ACS Publications
Here, six phenanthrene (the smallest arm-chair graphene nanoribbon) derivatives with
dithiomethyl substitutions at different positions as the anchoring groups were synthesized …

Precise Regulation of Ultralow Conductance Attenuation in Single-Molecule Hexabenzocoronene Oligomers

M Zhang, B Wang, H Jia, C Zhao, J Hao… - ACS Materials …, 2024 - ACS Publications
Efficient long-range charge transport within molecular wires, which hinges upon ultralow
length-dependent conductance attenuation, is essential for molecular electronics and …

Collection of unconventional transport phenomena: natural obstacle or vibrant guiding principle for the design of molecular junctions?

J Ren, T Li, Z Li, D Kong, G Shan, KP Dou - AAPPS Bulletin, 2024 - Springer
The real atomic scale details of molecular junctions would be of much complexity and can
yield a plethora of “counterintuitive” results. Here, we provide an overview of four …

Delocalization-assisted transport through nucleic acids in molecular junctions

J Valdiviezo, C Clever, E Beall, A Pearse, Y Bae… - Biochemistry, 2021 - ACS Publications
The flow of charge through molecules is central to the function of supramolecular machines,
and charge transport in nucleic acids is implicated in molecular signaling and DNA repair …

Assessing the importance of multireference correlation in predicting reversed conductance decay

TA Cossaboon, S Kazmi, M Tineo… - Physical Chemistry …, 2024 - pubs.rsc.org
In a classical electronic resistor, conductance decays as the device length increases
according to Ohm's Law. While most molecular series display a comparable exponential …

Steric Effects on Single‐Molecule Conductance in Flat‐Lying Phenanthrene

K Batzinger, Q Zhou, X Ye, E Borguet… - … A European Journal, 2024 - Wiley Online Library
A previous combined experimental and theoretical study found that the position of anchoring
groups on a phenanthrene (PHE) backbone played a large role in determining the single …

Anti-ohmic nanoconductors: myth, reality and promise

A Bajaj, ME Ali - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
The recent accomplishment in the design of molecular nanowires characterized by
increasing conductance with length has led to the origin of an extraordinary new family of …

Bridge Effect on Molecular Rectification: Linearly Conjugated, Cross-Conjugated, and Saturated Bridges

VJ Santamaría-García, J Bonilla-Ríos… - The Journal of Physical …, 2023 - ACS Publications
The bridge is a crucial component of the donor-bridge-acceptor (DBA) architecture when
studying electron transport properties and molecular electronics. In this work, we explore the …

Unraveling the Push‐Pull Effect in Acenes, Polyenes and Polyynes

PA Wieczorkiewicz, M Shahamirian… - … A European Journal, 2024 - Wiley Online Library
Substituent effects (SEs) are fundamental for predicting molecular reactivity, while polyene,
polyyne and acene derivatives are precursors to compounds with diverse applications …