Recent progress on synthesis and structural aspects of rare-earth phosphates

SN Achary, S Bevara, AK Tyagi - Coordination Chemistry Reviews, 2017 - Elsevier
In this article a brief review of recent progress on preparation and crystal chemistry of rare-
earth phosphates have been presented. The article begins with a brief note on the rare …

[書籍][B] Theoretical spectroscopy of transition metal and rare earth ions: from free state to crystal field

MG Brik, M Chong-Geng - 2019 - taylorfrancis.com
This book describes in detail the main concepts of theoretical spectroscopy of transition
metal and rare-earth ions. It shows how the energy levels of different electron configurations …

Preparation and properties of Eu 2+/Eu 3+ co-activated Ca 9 Lu (PO 4) 7 phosphors for multichannel photoluminescence

W Ruan, M **e, Q Yang, L Hu, K Su - Inorganic Chemistry Frontiers, 2022 - pubs.rsc.org
A series of single-phase white light-emitting phosphors Ca9Lu (PO4) 7: xEu2+/3+(x= 0.01–
0.2) were successfully synthesized by a general high-temperature solid-state reaction in a …

Synthesis, neutron diffraction and photoluminescence properties of a whitlockite structured Ca9MgLi (PO4) 7: Pr3+ phosphor

OP Golim, S Huang, L Yin, T Yang, H Zhou, W Gao… - Ceramics …, 2020 - Elsevier
The whitlockite structured compound Ca 9 MgLi (PO 4) 7 has been investigated as a
potential host material for down-conversion phosphors. However, no detailed crystal …

Spectroscopic Distinctions between Two Types of Ce3+ Ions in X2-Y2SiO5: A Theoretical Investigation

J Wen, CK Duan, L Ning, Y Huang, S Zhan… - The Journal of …, 2014 - ACS Publications
The Ce3+ ions occupying the two crystallographically distinct Y3+ sites both with C 1 point
group symmetry in the X2-Y2SiO5 (X2-YSO) crystal are discriminated by their spectroscopic …

Synthesis, structural model and vibrational spectroscopy of lutetium tricalcium phosphate Ca9Lu (PO4) 7

F Capitelli, M Rossi, A ElKhouri, M Elaatmani… - Journal of Rare …, 2018 - Elsevier
Lutetium β-tricalcium phosphate Ca 9 Lu (PO 4) 7 was synthesized by solid-state reaction at
1200° C, and investigated by means of a combination of scanning electron microscopy …

Structural and spectroscopic features of Ca9M (PO4) 7 (M= Al3+, Lu3+) whitlockites doped with Pr3+ ions

A Watras, I Carrasco, R Pazik, RJ Wiglusz… - Journal of Alloys and …, 2016 - Elsevier
In this work we present the structural and spectroscopic properties of Ca 9 M (PO 4) 7 (M=
Al, Lu) whitlockite compounds doped with Pr 3+ ions. The Al containing samples were …

Structural study of Yb3+, Eu3+ and Pr3+ doped Ca9Lu (PO4) 7

F Piccinelli, M Trevisani, JR Plaisier, M Bettinelli - Journal of Rare Earths, 2015 - Elsevier
The whitlockite-like crystal structure of Ca 9 Lu (PO 4) 7 when doped with several ions (Yb
3+, Eu 3+ and Pr 3+) at different concentrations (1 mol.%, 5 mol.% and 10 mol.%) was …

Vacuum ultraviolet spectroscopic analysis of Ce3+-doped hexagonal YPO4· 0.8 H2O based on exchange charge model

CG Ma, AV Popov, AS Vanetsev, OM Gaitko… - Journal of …, 2014 - Elsevier
Abstract The hexagonal YPO 4· 0.8 H 2 O: Ce 3+ nanophosphors are successfully prepared
by the microwave–hydrothermal technique for the first time. The 4f–5d excitation spectrum of …

Spin–orbit coupling and quasi–nephelauxetic effect in Ce3+

DN Petrov, BM Angelov - Physica B: Condensed Matter, 2020 - Elsevier
A quasi-nephelauxetic effect has been found in Ce 3+ ions in different crystal matrices by
employing spin-orbit interaction for the ground level 2 F 5/2. The corresponding matrix …