Vibrational spectroscopic map, vibrational spectroscopy, and intermolecular interaction

CR Baiz, B Błasiak, J Bredenbeck, M Cho… - Chemical …, 2020 - ACS Publications
Vibrational spectroscopy is an essential tool in chemical analyses, biological assays, and
studies of functional materials. Over the past decade, various coherent nonlinear vibrational …

Transparent window 2D IR spectroscopy of proteins

MC Thielges - The Journal of chemical physics, 2021 - pubs.aip.org
Proteins are complex, heterogeneous macromolecules that exist as ensembles of
interconverting states on a complex energy landscape. A complete, molecular-level …

Probing the Hydrophobic Region of a Lipid Bilayer at Specific Depths Using Vibrational Spectroscopy

MM Islam, SU Nawagamuwage… - Journal of the …, 2023 - ACS Publications
A novel spectroscopic approach for studying the flexibility and mobility in the hydrophobic
interior of lipid bilayers at specific depths is proposed. A set of test compounds featuring an …

Multidimensional Widefield Infrared-Encoded Spontaneous Emission Microscopy: Distinguishing Chromophores by Ultrashort Infrared Pulses

C Yan, C Wang, JC Wagner, J Ren, C Lee… - Journal of the …, 2023 - ACS Publications
Photoluminescence (PL) imaging has broad applications in visualizing biological activities,
detecting chemical species, and characterizing materials. However, the chemical …

Giant Photon‐Drag‐Induced Ultrafast Photocurrent in Diamond for Nonlinear Photonics

X Xue, W Du, W Tao, Y Huang, Z Lei… - Laser & Photonics …, 2024 - Wiley Online Library
Diamond is emerging as an attractive third‐generation wide‐bandgap semiconductor for
future on‐chip nonlinear photonics and quantum optics due to its unique thermal, optical …

Effect of isotope substitution on the Fermi resonance and vibrational lifetime of unnatural amino acids modified with IR probe: A 2D-IR and pump-probe study of 4 …

JY Park, S Mondal, HJ Kwon, PK Sahu… - The Journal of …, 2020 - pubs.aip.org
The infrared (IR) probe often suffers from an unexpected complex absorption profile due to
the Fermi resonance and short vibrational lifetime, which restricts the application of time …

Site-specific protein dynamics probed by ultrafast infrared spectroscopy of a noncanonical amino acid

CR Hall, J Tolentino Collado, JN Iuliano… - The Journal of …, 2019 - ACS Publications
Real-time observation of structure changes associated with protein function remains a major
challenge. Ultrafast pump-probe methods record dynamics in light activated proteins, but the …

Signatures of coherent vibrational dynamics in ethylene carbonate

L Guerrieri, S Hall, BM Luther… - The Journal of Chemical …, 2024 - pubs.aip.org
Despite having practical applications in battery technology and serving as a model system
for Fermi resonance coupling, ethylene carbonate (EC) receives little direct attention as a …

Unraveling Hydration Shell Dynamics and Viscosity Effects Around Cyanamide Probes via 2D IR Spectroscopy

CJ Mallon, M Hassani, EH Osofsky… - Journal of the …, 2024 - ACS Publications
Hydration dynamics and solvent viscosity play critical roles in the structure and function of
biomolecules. An overwhelming body of evidence suggests that protein and membrane …

Tuning molecular vibrational energy flow within an aromatic scaffold via anharmonic coupling

AJ Schmitz, HD Pandey, F Chalyavi, T Shi… - The Journal of …, 2019 - ACS Publications
From guiding chemical reactivity in synthesis or protein folding to the design of energy
diodes, intramolecular vibrational energy redistribution harnesses the power to influence the …