Structure: function relationships in molecular spin-crossover complexes

MA Halcrow - Chemical Society Reviews, 2011 - pubs.rsc.org
Spin-crossover compounds are becoming increasingly popular for device and sensor
applications, and in soft materials, that make use of their switchable colour, paramagnetism …

Distortion pathways of transition metal coordination polyhedra induced by chelating topology

S Alvarez - Chemical Reviews, 2015 - ACS Publications
A continuous shape measures analysis of the coordination polyhedra of a host of transition
metal complexes with bi-and multidentate ligands discloses the distortion pathway …

Iron (II) complexes of 2, 6-di (pyrazol-1-yl) pyridines—A versatile system for spin-crossover research

MA Halcrow - Coordination Chemistry Reviews, 2009 - Elsevier
Synthetic procedures are available for the derivatisation of almost every position of the 2, 6-
di (pyrazol-1-yl) pyridine (1-bpp) skeleton. This has led to the preparation of a large number …

First Step Towards a Devil's Staircase in Spin‐Crossover Materials

E Trzop, D Zhang, L Piñeiro‐Lopez… - Angewandte …, 2016 - Wiley Online Library
The unprecedented bimetallic 2D coordination polymer {Fe [(Hg (SCN) 3) 2](4, 4′‐bipy) 2}
n exhibits a thermal high‐spin (HS)↔ low‐spin (LS) staircase‐like conversion characterized …

Elucidating the mechanism of a two-step spin transition in a nanoporous metal− organic framework

GJ Halder, KW Chapman, SM Neville… - Journal of the …, 2008 - ACS Publications
The nanoporous metal− organic framework, Fe (bpe) 2 (NCS) 2· 3 (acetone), SCOF-4
(Ac)(where bpe is 1, 2-bis (4′-pyridyl) ethane), displays a two-step spin crossover (SCO) …

Electronic control of spin-crossover properties in four-coordinate bis (formazanate) iron (II) complexes

F Milocco, F De Vries, IMA Bartels… - Journal of the …, 2020 - ACS Publications
The transition between spin states in d-block metal complexes has important ramifications
for their structure and reactivity, with applications ranging from information storage materials …

Electronic vs. structural ordering in a manganese (III) spin crossover complex

AJ Fitzpatrick, E Trzop, H Müller-Bunz… - Chemical …, 2015 - pubs.rsc.org
A symmetry breaking spin transition in a Mn (III) complex is reported with three structural
phases, a high symmetry high temperature S= 2 phase, an intermediate S= 1/S= 2 ordered …

A Symmetry‐Breaking Spin‐State Transition in Iron (III)

M Griffin, S Shakespeare, HJ Shepherd… - Angewandte Chemie …, 2011 - Wiley Online Library
Molecular spin crossover (SCO) has been intensively studied over the last 20 years,
motivated both by the need to develop improved understanding of the phenomenon and in …

Multi‐Step Spin Crossover Accompanied by Symmetry Breaking in an FeIII Complex: Crystallographic Evidence and DFT Studies

ZY Li, JW Dai, Y Shiota, K Yoshizawa… - … A European Journal, 2013 - Wiley Online Library
Molecular bistability plays an important role in develo** advanced materials for
applications such as molecularlevel sensors, switches, and memory. Therefore, molecular …

Direct Observation of Ordered High‐Spin–Low‐Spin Intermediate States of an Iron (III) Three‐Step Spin‐Crossover Complex

ZY Li, H Ohtsu, T Kojima, JW Dai, T Yoshida… - Angewandte …, 2016 - Wiley Online Library
A neutral mononuclear FeIII complex [FeIII (H‐5‐Br‐thsa‐Me)(5‐Br‐thsa‐Me)]⋅ H2O (1; H2‐
5‐Br‐thsa‐Me= 5‐bromosalicylaldehyde methylthiosemicarbazone) was prepared that …