Marriage of heavy main group elements with π-conjugated materials for optoelectronic applications

SM Parke, MP Boone, E Rivard - Chemical Communications, 2016 - pubs.rsc.org
This review article summarizes recent progress in the synthesis and optoelectronic
properties of conjugated materials containing heavy main group elements from Group 13 …

[BUCH][B] Main group strategies towards functional hybrid materials

T Baumgartner, F Jäkle - 2018 - books.google.com
Showcases the highly beneficial features arising from the presence of main group elements
in organic materials, for the development of more sophisticated, yet simple advanced …

Recent advances in π-conjugated N^ C-chelate organoboron materials

A Haque, RA Al-Balushi, PR Raithby, MS Khan - Molecules, 2020 - mdpi.com
Boron-containing π-conjugated materials are archetypical candidates for a variety of
molecular scale applications. The incorporation of boron into the π-conjugated frameworks …

Directed Iron-Catalyzed ortho-Alkylation and Arylation: Toward the Stereoselective Catalytic Synthesis of 1,2-Disubstituted Planar-Chiral Ferrocene Derivatives

D Schmiel, H Butenschön - Organometallics, 2017 - ACS Publications
The iron-catalyzed directed ortho-functionalization of arenes developed to an important
method in the field of C–H activation. On the other hand, the iron-catalyzed ortho …

Heteroatom-Bridged ortho-Biferrocenes: Stereoselective Synthesis, Structural Features, and Electrochemical Properties

J Chen, AC Tagne Kuate, RA Lalancette… - Organometallics, 2016 - ACS Publications
A versatile synthetic protocol is described for the synthesis of heteroatom-bridged
biferrocene derivatives, including the symmetric species 2-SnSn and the planar-chiral …

Electron Transfer in Mixed‐Valence Ferrocenyl‐Functionalized Five‐and Six‐Membered Heterocycles

P Frenzel, HAQ Lang - Mixed‐Valence Systems: Fundamentals …, 2023 - Wiley Online Library
Electrostatic interactions between mainly redox‐active bi‐and multi‐ferrocenyl [= Fe (η 5‐C
5 H 4)(η 5‐C 5 H 5)] functionalized five‐and six‐membered anti‐aromatic and aromatic …

(2Sp,4R,8Sp)-4-Methyl-1-phenyl-diferroceno-5-Z-ethylene-1-phosphinoxide

P Honegger, M Widhalm - Molbank, 2020 - mdpi.com
We present a synthesis of the title compound, a homochiral diferroceno cycle intended for
use in asymmetric catalysis. We present a hydrovinylation protocol, which allows the …

A Computational Investigation Of Cope-Type Eliminations Of Beta-Borylated Sulfoxides And Amine Oxides

E Nicol - 2025 - atrium.lib.uoguelph.ca
This thesis explores the effects of the addition of boron-based functional groups on two main
classes of reactions: the internal elimination of sulfoxides and Cope-type reactions of amine …

Construction of hydrogen-bonded networks of 1′, 1‴-diboronic acids of biferrocene and biferrocenium cation

K Tahara, T Akita, S Yabumoto, N Terashita… - Journal of …, 2016 - Elsevier
The solid-state structures of 1′, 1‴-biferrocenediboronic acid (1) were elucidated by X-ray
crystallography, to obtain insight into controlling the structures of hydrogen-bonded (H …

Germanium and Tin in Conjugated Organic Materials

Y Adachi, J Ohshita - Main Group Strategies towards Functional …, 2017 - Wiley Online Library
Tuning the electronic states and properties of conjugated compounds by element
substitution can impart organic materials with desired functionality. Replacing silicon with …