Molecular views on mechanisms of Brønsted acid-catalyzed reactions in zeolites

C Chizallet, C Bouchy, K Larmier… - Chemical …, 2023 - ACS Publications
The Brønsted acidity of proton-exchanged zeolites has historically led to the most impactful
applications of these materials in heterogeneous catalysis, mainly in the fields of …

Continuous Flow Upgrading of Selected C2–C6 Platform Chemicals Derived from Biomass

R Gerardy, DP Debecker, J Estager, P Luis… - Chemical …, 2020 - ACS Publications
The ever increasing industrial production of commodity and specialty chemicals inexorably
depletes the finite primary fossil resources available on Earth. The forecast of population …

Synergistic catalysis for promoting ring-opening hydrogenation of biomass-derived cyclic oxygenates

Z Zhao, C Yang, P Sun, G Gao, Q Liu, Z Huang… - ACS Catalysis, 2023 - ACS Publications
Biomass has attracted great attention as a carbon source for the production of valuable
chemicals and fuels. Selective ring-opening hydrogenation of cyclic oxygenates derived …

Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy's “Top 10” revisited

JJ Bozell, GR Petersen - Green chemistry, 2010 - pubs.rsc.org
A biorefinery that supplements its manufacture of low value biofuels with high value
biobased chemicals can enable efforts to reduce nonrenewable fuel consumption while …

The potential of glycerol as a value-added commodity

M Anitha, SK Kamarudin, NT Kofli - Chemical Engineering Journal, 2016 - Elsevier
Glycerol is a by-product of biodiesel, soap and fatty acid manufacturing plants, which are
now facing sustainability threats and a reduction in prices in the market due to its oversupply …

Catalytic reforming of oxygenates: state of the art and future prospects

D Li, X Li, J Gong - Chemical reviews, 2016 - ACS Publications
This Review describes recent advances in the design, synthesis, reactivity, selectivity,
structural, and electronic properties of the catalysts for reforming of a variety of oxygenates …

Design of solid acid catalysts for aqueous-phase dehydration of carbohydrates: The role of Lewis and Brønsted acid sites

R Weingarten, GA Tompsett, WC Conner Jr… - Journal of Catalysis, 2011 - Elsevier
We have prepared a series of well-characterized acid catalysts, including Zr–P, SiO2–
Al2O3, WOX/ZrO2, γ-Al2O3, and HY zeolite and tested them for aqueous-phase dehydration …

Glycerol dehydration to acrolein in the context of new uses of glycerol

B Katryniok, S Paul, V Bellière-Baca, P Rey… - Green …, 2010 - pubs.rsc.org
Catalytic dehydration of glycerol to acrolein has the potential to valorise the glut of crude
glycerol issuing from biodiesel production. This reaction requires catalysts with appropriate …

Recent developments in the field of catalytic dehydration of glycerol to acrolein

B Katryniok, S Paul, F Dumeignil - Acs Catalysis, 2013 - ACS Publications
Catalytic dehydration is one of the possible reactions to valorize the large amounts of
glycerol yielding from the transesterification process. Thus, since the biodiesel boom in 2004 …

Supported MoOx and WOx Solid Acids for Biomass Valorization: Interplay of Coordination Chemistry, Acidity, and Catalysis

P Sudarsanam, NK Gupta, B Mallesham, N Singh… - Acs …, 2021 - ACS Publications
Supported molybdenum oxide (MoO x) and tungsten oxide (WO x) materials are a vital class
of solid acid catalysts for the chemical industry because of their nontoxic nature, strong …