Manipulating matter by strong coupling to vacuum fields

FJ Garcia-Vidal, C Ciuti, TW Ebbesen - Science, 2021 - science.org
BACKGROUND One of the most important phenomena in cavity quantum electrodynamics
(cQED) is the so-called strong coupling regime, which appears when the interaction …

Control, modulation, and analytical descriptions of vibrational strong coupling

BS Simpkins, AD Dunkelberger, I Vurgaftman - Chemical Reviews, 2023 - ACS Publications
Here, we review the design of optical cavities, transient and modulated responses, and
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …

Molecular polaritons for chemistry, photonics and quantum technologies

B **ang, W **ong - Chemical Reviews, 2024 - ACS Publications
Molecular polaritons are quasiparticles resulting from the hybridization between molecular
and photonic modes. These composite entities, bearing characteristics inherited from both …

Molecular chemistry in cavity strong coupling

K Hirai, JA Hutchison, H Uji-i - Chemical Reviews, 2023 - ACS Publications
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …

Chemistry under vibrational strong coupling

K Nagarajan, A Thomas… - Journal of the American …, 2021 - ACS Publications
Over the past decade, the possibility of manipulating chemistry and material properties using
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …

Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

Vibration-cavity polariton chemistry and dynamics

AD Dunkelberger, BS Simpkins… - Annual review of …, 2022 - annualreviews.org
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …

Gradient High‐Q Dielectric Metasurfaces for Broadband Sensing and Control of Vibrational Light‐Matter Coupling

FU Richter, I Sinev, S Zhou, A Leitis, SH Oh… - Advanced …, 2024 - Wiley Online Library
Surface‐enhanced infrared absorption spectroscopy (SEIRA) has emerged as a powerful
technique for ultrasensitive chemical‐specific analysis. SEIRA can be realized by employing …

Non‐Polaritonic Effects in Cavity‐Modified Photochemistry

PA Thomas, WJ Tan, VG Kravets… - Advanced …, 2024 - Wiley Online Library
Strong coupling of molecules to vacuum fields is widely reported to lead to modified
chemical properties such as reaction rates. However, some recent attempts to reproduce …

RETRACTED: Solvent polarity under vibrational strong coupling

M Piejko, B Patrahau, K Joseph, C Muller… - Journal of the …, 2023 - ACS Publications
Vibrational strong coupling (VSC) occurs when molecular vibrations hybridize with the
modes of an optical cavity, an interaction mediated by vacuum fluctuations. VSC has been …