RNA structural dynamics as captured by molecular simulations: a comprehensive overview

J Sponer, G Bussi, M Krepl, P Banáš, S Bottaro… - Chemical …, 2018 - ACS Publications
With both catalytic and genetic functions, ribonucleic acid (RNA) is perhaps the most
pluripotent chemical species in molecular biology, and its functions are intimately linked to …

Fundamental studies of functional nucleic acids: aptamers, riboswitches, ribozymes and DNAzymes

R Micura, C Höbartner - Chemical Society Reviews, 2020 - pubs.rsc.org
This review aims at juxtaposing common versus distinct structural and functional strategies
that are applied by aptamers, riboswitches, and ribozymes/DNAzymes. Focusing on recently …

Rational evolution of Cd2+-specific DNAzymes with phosphorothioate modified cleavage junction and Cd2+ sensing

PJJ Huang, J Liu - Nucleic Acids Research, 2015 - academic.oup.com
In vitro selection of RNA-cleaving DNAzymes is a powerful method for isolating metal-
specific DNA. A few successful examples are known, but it is still difficult to target some …

An Ultrasensitive Light-up Cu2+ Biosensor Using a New DNAzyme Cleaving a Phosphorothioate-Modified Substrate

PJJ Huang, J Liu - Analytical chemistry, 2016 - ACS Publications
Cu2+ is a very important metal ion in biology, environmental science, and industry.
Develo** biosensors for Cu2+ is a key topic in analytical chemistry. DNAzyme-based …

Force Field for Mg2+, Mn2+, Zn2+, and Cd2+ Ions That Have Balanced Interactions with Nucleic Acids

MT Panteva, GM Giambasu… - The Journal of Physical …, 2015 - ACS Publications
Divalent metal ions are of fundamental importance to the function and folding of nucleic
acids. Divalent metal ion–nucleic acid interactions are complex in nature and include both …

Phosphorothioate nucleic acids for probing metal binding, biosensing and nanotechnology

R Saran, Z Huang, J Liu - Coordination Chemistry Reviews, 2021 - Elsevier
Phosphorothioate (PS) modification replaces one of the non-bridging oxygen atoms by
sulfur in the phosphate backbone of nucleic acids. While PS DNAs have been traditionally …

In vitro selection of chemically modified DNAzymes

PJJ Huang, J Liu - ChemistryOpen, 2020 - Wiley Online Library
DNAzymes are in vitro selected DNA oligonucleotides with catalytic activities. RNA cleavage
is one of the most extensively studied DNAzyme reactions. To expand the chemical …

Unveiling the sulfur–sulfur bridge: Accurate structural and energetic characterization of a homochalcogen intermolecular bond

DA Obenchain, L Spada, S Alessandrini… - Angewandte Chemie …, 2018 - Wiley Online Library
By combining rotational spectroscopy in supersonic expansion with the capability of state‐of‐
the‐art quantum‐chemical computations in accurately determining structural and energetic …

Insights into DNA catalysis from structural and functional studies of the 8-17 DNAzyme

M Cepeda-Plaza, A Peracchi - Organic & Biomolecular Chemistry, 2020 - pubs.rsc.org
DNAzymes (deoxyribozymes) are single-stranded DNA molecules endowed with catalytic
activity, obtained by in vitro selection. In the past 25 years, dozens of DNAzymes have been …

A new heavy lanthanide-dependent DNAzyme displaying strong metal cooperativity and unrescuable phosphorothioate effect

PJJ Huang, M Vazin, Ż Matuszek, J Liu - Nucleic acids research, 2015 - academic.oup.com
In vitro selection of RNA-cleaving DNAzymes was performed using three heavy lanthanide
ions (Ln3+): Ho3+, Er3+ and Tm3+. The resulting sequences were aligned together and …