Chemical reactivity and solution structure: on the way to a paradigm shift?
LO Kononov - RSC advances, 2015 - pubs.rsc.org
Recent studies unveiled two unprecedented phenomena which together may induce a
paradigm shift in understanding chemical reactivity in solutions which would no longer be …
paradigm shift in understanding chemical reactivity in solutions which would no longer be …
Phase transitions in soft matter induced by selective solvation
We review our recent studies on selective solvation effects in phase separation in polar
binary mixtures with a small amount of solutes. Such hydrophilic or hydrophobic particles …
binary mixtures with a small amount of solutes. Such hydrophilic or hydrophobic particles …
Criticality of ionic fluids
H Weingärtner, W Schröer - Advances in Chemical Physics, 2001 - Wiley Online Library
Criticality of ionic fluids Page 9 CRITICALITY OF IONIC FLUIDS HERMANN
WEINGARTNER Physikalische Chemie II, Ruhr-Universitat Bochum, Bochum, Germany …
WEINGARTNER Physikalische Chemie II, Ruhr-Universitat Bochum, Bochum, Germany …
Solvation effects in near-critical binary mixtures
A Onuki, H Kitamura - The Journal of chemical physics, 2004 - pubs.aip.org
A Ginzburg-Landau theory is presented to investigate solvation effects in near-critical polar
fluid binary mixtures. Concentration dependence of the dielectric constant gives rise to a …
fluid binary mixtures. Concentration dependence of the dielectric constant gives rise to a …
Mesoscale inhomogeneities in aqueous solutions of 3-methylpyridine and tertiary butyl alcohol
Motivated by controversies in the literature on the microscopic and mesoscopic structure of
some aqueous solutions, we have performed static and dynamic light-scattering …
some aqueous solutions, we have performed static and dynamic light-scattering …
Direct experimental observation of the aggregation of α-amino acids into 100–200 nm clusters in aqueous solution
D Hagmeyer, J Ruesing, T Fenske, HW Klein… - RSC …, 2012 - pubs.rsc.org
Spherical supramolecular aggregates of α-amino acids with a typical diameter of 100–200
nm are formed spontaneously after dissolution in water at a concentration of a few mM, ie …
nm are formed spontaneously after dissolution in water at a concentration of a few mM, ie …
Criticality in aqueous solutions of 3-methylpyridine and sodium bromide
We address a controversial issue regarding the nature of critical behavior in ternary
electrolyte solutions of water, 3-methylpyridine, and sodium bromide. Earlier light-scattering …
electrolyte solutions of water, 3-methylpyridine, and sodium bromide. Earlier light-scattering …
Microemulsion-like aggregation behaviour of an LCST-type ionic liquid in water
R Wang, W Leng, Y Gao, L Yu - RSC Advances, 2014 - pubs.rsc.org
The ionic liquid (IL), tetrabutylphosphonium trifluoroacetate ([P4444][CF3COO]) showed a
low critical solution temperature (LCST)-type phase transition in water. It was found that …
low critical solution temperature (LCST)-type phase transition in water. It was found that …
[HTML][HTML] Solvation of lithium ion in dimethoxyethane and propylene carbonate
V Chaban - Chemical Physics Letters, 2015 - Elsevier
Solvation of the lithium ion (Li+) in dimethoxyethane (DME) and propylene carbonate (PC) is
of scientific significance and urgency in the context of lithium-ion batteries. I report PM7-MD …
of scientific significance and urgency in the context of lithium-ion batteries. I report PM7-MD …
Experimental evidence for crossover to mean-field tricritical behavior in a concentrated salt solution
We have discovered a mean-field multicritical point on the critical locus in an aqueous
solution of 3-methylpyridine and sodium bromide. Light-scattering measurements indicate …
solution of 3-methylpyridine and sodium bromide. Light-scattering measurements indicate …