One of the most exciting developments in the areas of catalysis, organometallic chemistry,
and polymer science in recent years has been the intense exploration and …

Metallocenes are very versatile catalysts for the production of polyolefins, polystyrene and
copolymers. Some polymers such as syndiotactic polypropene, syndiotactic polystyrene …

Work in the field of application of metallocene‐based catalysis in olefin, diolefin and styrene
polymerization has become a research topic of growing interest in recent years. A great …

Single-site homogeneous catalysts need to be activated by a co-catalyst or counterion. The
high activity imparted by methylaluminoxane (MAO) has caused it to be one of the most …

Since its discovery, methylalumoxane (MAO) has become of great importance as a
cocatalyst in homogeneous olefin polymerization. The working principles of single‐site …

In this review, various synthetic and structural aspects of methylaluminoxane and the
elementary processes involved in olefin polymerization, as identified by various …

Cp2Zr (13CH3) 2 (1) has been used as a probe for the reactivity of metallocene−
methylaluminoxane catalysts for olefin polymerization. A 1H and 13C NMR study of the …

Homogeneous zirconocene catalysts for olefin polymerization are very important. The
current standard procedure for the polymerization of ethene using this catalysts is the …

During the last two decades there has been considerable growth in the development of
electrospray ionization mass spectrometry (ESI‐MS) as a practical method for studying …

The UV/visible spectrum of the rac‐Et (Ind) 2ZrCl2/methylaluminoxane (MAO) catalytic
system in toluene at 20° C, which is related to the 'ligand to metal charge transfer'bands …