Mechanisms for DNA charge transport

JC Genereux, JK Barton - Chemical reviews, 2010 - ACS Publications
DNA charge transport (CT) chemistry has received considerable attention by scientific
researchers over the past 15 years since our first provocative publication on long-range CT …

Hole transfer kinetics of DNA

K Kawai, T Majima - Accounts of chemical research, 2013 - ACS Publications
Not long after the discovery of the double-helical structure of DNA in 1952, researchers
proposed that charge transfer along a one-dimensional π-array of nucleobases might be …

DNA-mediated charge transport in redox sensing and signaling

JC Genereux, AK Boal, JK Barton - Journal of the American …, 2010 - ACS Publications
The transport of charge through the DNA base-pair stack offers a route to carry out redox
chemistry at a distance. Here we describe characteristics of this chemistry that have been …

Sequence-independent and rapid long-range charge transfer through DNA

K Kawai, H Kodera, Y Osakada, T Majima - Nature Chemistry, 2009 - nature.com
Interest in using DNA as a building block for nanoelectronic sensors and devices stems from
its efficient hole-conducting properties and the relative ease with which it can be organized …

Solution, surface, and single molecule platforms for the study of DNA-mediated charge transport

NB Muren, ED Olmon, JK Barton - Physical chemistry chemical physics, 2012 - pubs.rsc.org
The structural core of DNA, a continuous stack of aromatic heterocycles, the base pairs,
which extends down the helical axis, gives rise to the fascinating electronic properties of this …

Charge transport across DNA-based three-way junctions

RM Young, APN Singh, AK Thazhathveetil… - Journal of the …, 2015 - ACS Publications
DNA-based molecular electronics will require charges to be transported from one site within
a 2D or 3D architecture to another. While this has been shown previously in linear, π …

Direct measurement of the dynamics of excess electron transfer through consecutive thymine sequence in DNA

MJ Park, M Fujitsuka, K Kawai… - Journal of the American …, 2011 - ACS Publications
Charge transfer in DNA is an essential process in biological systems because of its close
relation to DNA damage and repair. DNA is also an important material used in …

Theoretical and experimental study of charge transfer through DNA: impact of mercury mediated T-Hg-T base pair

I Kratochvilova, M Golan, M Vala… - The Journal of …, 2014 - ACS Publications
DNA-Hg complexes may play an important role in sensing DNA defects or in detecting the
presence of Hg in the environment. A fundamental way of characterizing DNA-Hg …

[HTML][HTML] Applications of ruthenium complexes covalently linked to nucleic acid derivatives

M Flamme, E Clarke, G Gasser, M Hollenstein - Molecules, 2018 - mdpi.com
Oligonucleotides are biopolymers that can be easily modified at various locations. Thereby,
the attachment of metal complexes to nucleic acid derivatives has emerged as a common …

Electronic and Nuclear Quantum Effects on Proton Transfer Reactions of Guanine–Thymine (GT) Mispairs Using Combined Quantum Mechanical/Molecular …

Y Tao, TJ Giese, DM York - Molecules, 2024 - mdpi.com
Rare tautomeric forms of nucleobases can lead to Watson–Crick-like (WC-like) mispairs in
DNA, but the process of proton transfer is fast and difficult to detect experimentally. NMR …