Conspectus Coordination-driven self-assembly can produce large, symmetrical, hollow
cages that are synthetically easy to access. The functions provided by these aesthetically …

As compared to porous network solids, including metal–organic frameworks, covalent–
organic frameworks, porous aromatic frameworks, and zeolites, porous molecular materials …

The binding of multiple guests by a single entity can lead to new modes of host–guest
interactions and thus new applications in, for example, catalysis and sensing. With the aim of …

During the past few decades, fabrication of multistep fluorescence-resonance energy
transfer (FRET) systems has become one of the most attractive topics within supramolecular …

Transformations within container-molecules provide a good alternative between traditional
homogeneous and heterogeneous catalysis, as the containers themselves can be regarded …

The expression of biological functions, such as enzyme catalysis, immune response, and
cargo transport in confined nanospaces, with very different physical and chemical …

The potential applications of metal–organic cages (MOCs) are mostly achieved through
specific host–guest interactions within their cavities. Electronic applications would require an …

Organic (porous) and metal–organic cages are promising biomimetic platforms with diverse
applications spanning recognition, sensing, and catalysis. The key to the emergence of …

The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …

A strategy to engineer the stacking of diketopyrrolopyrrole (DPP) dyes based on non‐
statistical metallosupramolecular self‐assembly is introduced. For this, the DPP backbone is …