In recent years, transition‐metal‐catalyzed C− H activation has become a key strategy in the
field of organic synthesis. Rhodium complexes are widely used as catalysts in a variety of …

Transition-metal-catalyzed nucleophilic addition of organometallic reagents to polar
unsaturated substrates is one of the most important and powerful bond-forming strategies …

Sequential reactions, through the incorporation of several distinct transformations into one
single sequence, are one of the most powerful synthetic tools in modern organic chemistry …

Reported herein is the metal-catalyzed regioselective C–H functionalization of quinoline N-
oxides at the 8-position: direct iodination and amidation were developed using rhodium and …

The terminal‐selective, remote C (sp3)− H alkylation of alkenes was achieved by a relay
process combining NiH‐catalyzed hydrometalation, chain walking, and alkylation. This …

The Rh (III)-catalyzed C-8 selective direct alkylation and alkynylation of quinoline N-oxides
has been developed. The reactions proceeded highly efficiently at room temperature over a …

Reported herein is an unprecedented base‐promoted deborylative alkylation of pyridine N‐
oxides using 1, 1‐diborylalkanes as alkyl sources. The reaction proceeds efficiently for a …

Various rhodium-catalyzed double C–H activations are reviewed. These powerful strategies
have been developed to construct C–C bonds, which might be widely embedded in complex …

The first example of Rh (III)-catalyzed cyclization of arylnitrones to indolines under external
oxidant-free conditions is presented. An intermolecular coupling of arylnitrones with internal …

In the presence of catalytic [Ru (p‐cym) I2] 2 and the base guanidine carbonate, benzoic
acids react with internal alkynes to give the corresponding 2‐vinylbenzoic acids. This alkyne …