Kinetics and mechanisms of catalytic water oxidation

S Fukuzumi, YM Lee, W Nam - Dalton Transactions, 2019 - pubs.rsc.org
The kinetics and mechanisms of thermal and photochemical oxidation of water with
homogeneous and heterogeneous catalysts, including conversion from homogeneous to …

The Middle‐Earth between Homogeneous and Heterogeneous Catalysis in Water Oxidation with Iridium

A Macchioni - European Journal of Inorganic Chemistry, 2019 - Wiley Online Library
Water oxidation (WO) is considered the ideal reaction to provide electrons and protons for
the photo‐and electrosynthesis of renewable fuels, generating exclusively O2 as a benign …

The influence of the ligand in the iridium mediated electrocatalyic water oxidation

B van Dijk, GM Rodriguez, L Wu, JP Hofmann… - ACS …, 2020 - ACS Publications
Electrochemical water oxidation is the bottleneck of electrolyzers as even the best catalysts,
iridium and ruthenium oxides, have to operate at significant overpotentials. Previously, the …

A Single Organoiridium Complex Generating Highly Active Catalysts for both Water Oxidation and NAD+/NADH Transformations

A Bucci, S Dunn, G Bellachioma… - ACS …, 2017 - ACS Publications
The complex [Cp* Ir (pica) Cl](1; pica= picolinamidate= κ2-pyridine-2-carboxamide) was
found to be an effective catalyst for both water oxidation to molecular oxygen and …

Extremely active, tunable, and pH-responsive iridium water oxidation catalysts

G Menendez Rodriguez, A Bucci… - ACS Energy …, 2017 - ACS Publications
The development of an efficient water oxidation catalyst is crucial in the framework of
constructing an artificial photo (electro) synthetic apparatus for the production of solar fuels …

Activating Kläui-type organometallic precursors at metal oxide surfaces for enhanced solar water oxidation

X Wan, L Wang, CL Dong… - ACS Energy …, 2018 - ACS Publications
Activating molecular catalysts at the surface of metal oxides can be a promising strategy to
overcome the sluggish interfacial kinetics and enhance the efficiencies for photo (electro) …

Light-Driven Water Oxidation with the Ir-blue Catalyst and the Ru(bpy)32+/S2O82– Cycle: Photogeneration of Active Dimers, Electron-Transfer Kinetics, and Light …

A Volpe, C Tubaro, M Natali, A Sartorel… - Inorganic …, 2019 - ACS Publications
Light-driven water oxidation is achieved with the Ru (bpy) 32+/S2O82–cycle employing the
highly active Ir-blue water oxidation catalyst, namely, an IrIV, IV2 (pyalc) 2 μ-oxo-dimer …

Strong Ligand Stabilization Based on π‐Extension in a Series of Ruthenium Terpyridine Water Oxidation Catalysts

S Amthor, D Hernández‐Castillo… - … A European Journal, 2021 - Wiley Online Library
The substitution behavior of the monodentate Cl ligand of a series of ruthenium (II)
terpyridine complexes (terpyridine (tpy)= 2, 2′: 6′, 2′′‐terpyridine) has been …

Microenvironment regulation of Ru (bda) L2 catalyst incorporated in metal-organic framework for effective photo-driven water oxidation

J Feng, X Li, Y Luo, Z Su, M Zhong, B Yu… - Chinese Journal of …, 2023 - Elsevier
A Ru (bda) L 2 molecular catalyst (H 2 bda= 2, 2′-bipyridine-6, 6′-dicarboxylic acid, L
represents ligands) was incorporated into a UiO-66 metal-organic framework (MOF) as …

Iridium water oxidation catalysts based on pyridine‐carbene alkyl‐substituted ligands

I Corbucci, F Zaccaria, R Heath, G Gatto… - …, 2019 - Wiley Online Library
Iridium complexes bearing pyridine triazolylidene ligands with variable steric hindrance,
derived by the presence of an R group (R= H, Me, Et, nPr, iPr, Bu, and Oct) onto the N1 …