Electronic defects in metal oxide photocatalysts

E Pastor, M Sachs, S Selim, JR Durrant… - Nature Reviews …, 2022 - nature.com
A deep understanding of defects is essential for the optimization of materials for solar energy
conversion. This is particularly true for metal oxide photo (electro) catalysts, which typically …

Carriers, quasi-particles, and collective excitations in halide perovskites

J Fu, S Ramesh, JW Melvin Lim, TC Sum - Chemical Reviews, 2023 - ACS Publications
Halide perovskites (HPs) are potential game-changing materials for a broad spectrum of
optoelectronic applications ranging from photovoltaics, light-emitting devices, lasers to …

Exciton polaron formation and hot-carrier relaxation in rigid Dion–Jacobson-type two-dimensional perovskites

S Biswas, R Zhao, F Alowa, M Zacharias… - Nature Materials, 2024 - nature.com
The efficiency of two-dimensional Dion–Jacobson-type materials relies on the complex
interplay between electronic and lattice dynamics; however, questions remain about the …

The significance of polarons and dynamic disorder in halide perovskites

MJ Schilcher, PJ Robinson, DJ Abramovitch… - ACS Energy …, 2021 - ACS Publications
The development of halide perovskite semiconductors led to various technological
breakthroughs in optoelectronics, in particular in the areas of photovoltaics and light-emitting …

Coupling to octahedral tilts in halide perovskite nanocrystals induces phonon-mediated attractive interactions between excitons

N Yazdani, MI Bodnarchuk, F Bertolotti, N Masciocchi… - Nature Physics, 2024 - nature.com
Understanding the origin of electron–phonon coupling in lead halide perovskites is key to
interpreting and leveraging their optical and electronic properties. Here we show that …

Exciton dissociation in 2D layered metal-halide perovskites

A Simbula, L Wu, F Pitzalis, R Pau, S Lai, F Liu… - Nature …, 2023 - nature.com
Layered 2D perovskites are making inroads as materials for photovoltaics and light emitting
diodes, but their photophysics is still lively debated. Although their large exciton binding …

Polarons in two-dimensional atomic crystals

WH Sio, F Giustino - Nature Physics, 2023 - nature.com
Polarons are quasiparticles that emerge from the interaction of fermionic particles with
bosonic fields. In crystalline solids, polarons form when electrons and holes become …

Unraveling Size‐Dependent Ion‐Migration for Stable Mixed‐Halide Perovskite Light‐Emitting Diodes

Y Jiang, K Wei, C Sun, Y Feng, L Zhang… - Advanced …, 2023 - Wiley Online Library
Mixed‐halide perovskites show tunable emission wavelength across the visible‐light range,
with optimum control of the light color. However, color stability remains limited due to the …

Photocarrier-induced persistent structural polarization in soft-lattice lead halide perovskites

Q Qian, Z Wan, H Takenaka, JK Keum, TJ Smart… - Nature …, 2023 - nature.com
The success of the lead halide perovskites in diverse optoelectronics has motivated
considerable interest in their fundamental photocarrier dynamics. Here we report the …

Excitonic polarons and self-trapped excitons from first-principles exciton-phonon couplings

Z Dai, C Lian, J Lafuente-Bartolome, F Giustino - Physical Review Letters, 2024 - APS
Excitons consist of electrons and holes held together by their attractive Coulomb interaction.
Although excitons are neutral excitations, spatial fluctuations in their charge density couple …