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Electronic defects in metal oxide photocatalysts
A deep understanding of defects is essential for the optimization of materials for solar energy
conversion. This is particularly true for metal oxide photo (electro) catalysts, which typically …
conversion. This is particularly true for metal oxide photo (electro) catalysts, which typically …
Carriers, quasi-particles, and collective excitations in halide perovskites
Halide perovskites (HPs) are potential game-changing materials for a broad spectrum of
optoelectronic applications ranging from photovoltaics, light-emitting devices, lasers to …
optoelectronic applications ranging from photovoltaics, light-emitting devices, lasers to …
Exciton polaron formation and hot-carrier relaxation in rigid Dion–Jacobson-type two-dimensional perovskites
The efficiency of two-dimensional Dion–Jacobson-type materials relies on the complex
interplay between electronic and lattice dynamics; however, questions remain about the …
interplay between electronic and lattice dynamics; however, questions remain about the …
The significance of polarons and dynamic disorder in halide perovskites
The development of halide perovskite semiconductors led to various technological
breakthroughs in optoelectronics, in particular in the areas of photovoltaics and light-emitting …
breakthroughs in optoelectronics, in particular in the areas of photovoltaics and light-emitting …
Coupling to octahedral tilts in halide perovskite nanocrystals induces phonon-mediated attractive interactions between excitons
Understanding the origin of electron–phonon coupling in lead halide perovskites is key to
interpreting and leveraging their optical and electronic properties. Here we show that …
interpreting and leveraging their optical and electronic properties. Here we show that …
Exciton dissociation in 2D layered metal-halide perovskites
Layered 2D perovskites are making inroads as materials for photovoltaics and light emitting
diodes, but their photophysics is still lively debated. Although their large exciton binding …
diodes, but their photophysics is still lively debated. Although their large exciton binding …
Polarons in two-dimensional atomic crystals
Polarons are quasiparticles that emerge from the interaction of fermionic particles with
bosonic fields. In crystalline solids, polarons form when electrons and holes become …
bosonic fields. In crystalline solids, polarons form when electrons and holes become …
Unraveling Size‐Dependent Ion‐Migration for Stable Mixed‐Halide Perovskite Light‐Emitting Diodes
Mixed‐halide perovskites show tunable emission wavelength across the visible‐light range,
with optimum control of the light color. However, color stability remains limited due to the …
with optimum control of the light color. However, color stability remains limited due to the …
Photocarrier-induced persistent structural polarization in soft-lattice lead halide perovskites
The success of the lead halide perovskites in diverse optoelectronics has motivated
considerable interest in their fundamental photocarrier dynamics. Here we report the …
considerable interest in their fundamental photocarrier dynamics. Here we report the …
Excitonic polarons and self-trapped excitons from first-principles exciton-phonon couplings
Excitons consist of electrons and holes held together by their attractive Coulomb interaction.
Although excitons are neutral excitations, spatial fluctuations in their charge density couple …
Although excitons are neutral excitations, spatial fluctuations in their charge density couple …