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Theoretical modeling of electrochemical proton-coupled electron transfer
Proton-coupled electron transfer (PCET) plays an essential role in a wide range of
electrocatalytic processes. A vast array of theoretical and computational methods have been …
electrocatalytic processes. A vast array of theoretical and computational methods have been …
Dioxygen in polyoxometalate mediated reactions
In this review article, we consider the use of molecular oxygen in reactions mediated by
polyoxometalates. Polyoxometalates are anionic metal oxide clusters of a variety of …
polyoxometalates. Polyoxometalates are anionic metal oxide clusters of a variety of …
Proton-coupled electron transfer: Moving together and charging forward
Proton-coupled electron transfer (PCET) is ubiquitous throughout chemistry and biology.
This Perspective discusses recent advances and current challenges in the field of PCET …
This Perspective discusses recent advances and current challenges in the field of PCET …
Proton-coupled electron transfer
An initial review (PCET1) on proton-coupled electron transfer (PCET) by Huynh and Meyer
appeared in Chemical Reviews in 2007.(1) This is a follow-up on the original. It was …
appeared in Chemical Reviews in 2007.(1) This is a follow-up on the original. It was …
Theory of coupled electron and proton transfer reactions
Coupled electron and proton transfer reactions play a key role in the mechanisms of
biological energy transduction. 1-3 Such reactions are also fundamental for artificial …
biological energy transduction. 1-3 Such reactions are also fundamental for artificial …
Proton-coupled electron transfer
MHV Huynh, TJ Meyer - Chemical reviews, 2007 - ACS Publications
At the core of many important energy conversion processes in chemistry and biology are
oxidation-reduction reactions in which both electrons and protons are transferred. An …
oxidation-reduction reactions in which both electrons and protons are transferred. An …
Electrochemistry of redox-active self-assembled monolayers
Redox-active self-assembled monolayers (SAMs) provide an excellent platform for
investigating electron transfer kinetics. Using a well-defined bridge, a redox center can be …
investigating electron transfer kinetics. Using a well-defined bridge, a redox center can be …
Diradical generation via relayed proton-coupled electron transfer
Diradical generation followed by radical–radical cross-coupling is a powerful synthetic tool,
but its detailed mechanism has yet to be established. Herein, we proposed and confirmed a …
but its detailed mechanism has yet to be established. Herein, we proposed and confirmed a …
Proton-coupled electron transfer in solution, proteins, and electrochemistry
Recent advances in the theoretical treatment of proton-coupled electron transfer (PCET)
reactions are reviewed. These reactions play an important role in a wide range of biological …
reactions are reviewed. These reactions play an important role in a wide range of biological …
Hydrogen tunneling in enzymes and biomimetic models
Hydrogen transfer reactions play an important role throughout chemistry and biology. In
general, hydrogen transfer reactions encompass proton and hydride transfer, which are …
general, hydrogen transfer reactions encompass proton and hydride transfer, which are …