Chemical flexibility of atomically precise metal clusters

S Li, NN Li, XY Dong, SQ Zang, TCW Mak - Chemical Reviews, 2024 - ACS Publications
Ligand-protected metal clusters possess hybrid properties that seamlessly combine an
inorganic core with an organic ligand shell, imparting them exceptional chemical flexibility …

Molecularly engineered room-temperature phosphorescence for biomedical application: from the visible toward second near-infrared window

B Chang, J Chen, J Bao, T Sun, Z Cheng - Chemical Reviews, 2023 - ACS Publications
Phosphorescence, characterized by luminescent lifetimes significantly longer than that of
biological autofluorescence under ambient environment, is of great value for biomedical …

Circularly polarized luminescence in chiral materials

Y Zhang, S Yu, B Han, Y Zhou, X Zhang, X Gao, Z Tang - Matter, 2022 - cell.com
Due to their magnetic photophysical properties, circularly polarized luminescence (CPL)
materials are of particular interest. They have a wide range of potential applications in …

Engineering Au44 Nanoclusters for NIR-II Luminescence Imaging-Guided Photoactivatable Cancer Immunotherapy

G Yang, X Pan, W Feng, Q Yao, F Jiang, F Du, X Zhou… - ACS …, 2023 - ACS Publications
Immunotherapy is an advanced therapeutic strategy of cancer treatment but suffers from the
issues of off-target adverse effects, lack of real-time monitoring techniques, and …

Carborane-cluster-wrapped copper cluster with cyclodextrin-like cavities for chiral recognition

JH Huang, YJ Liu, Y Si, Y Cui, XY Dong… - Journal of the …, 2024 - ACS Publications
Chiral atomically precise metal clusters, known for their remarkable chiroptical properties,
hold great potential for applications in chirality recognition. However, advancements in this …

Metal-organic materials with circularly polarized luminescence

XY Luo, M Pan - Coordination Chemistry Reviews, 2022 - Elsevier
Chirality is ubiquitous in nature, and circularly polarized luminescence (CPL) is one of the
key features of some chiral non-racemic luminescent systems. Among the developed CPL …

Chiral Hydride Cu18 Clusters Transform to Superatomic Cu15Ag4 Clusters: Circularly Polarized Luminescence Lighting

MM Zhang, KK Gao, XY Dong, Y Si, T Jia… - Journal of the …, 2023 - ACS Publications
The manipulation of metal cluster enantiomers and their reconstruction remain challenging.
Here, for the first time, we report an enantiomeric pair of hydride copper clusters [Cu18H …

Molecule-like synthesis of ligand-protected metal nanoclusters

Q Yao, M Zhu, Z Yang, X Song, X Yuan… - Nature Reviews …, 2024 - nature.com
Ligand-protected metal nanoclusters (NCs) are ultrasmall particles (< 3 nm) that represent
the molecular state of metal materials. Owing to their molecule-like structure—particularly …

Achiral-Core-Metal Change in Isomorphic Enantiomeric Ag12Ag32 and Au12Ag32 Clusters Triggers Circularly Polarized Phosphorescence

YJ Kong, JH Hu, XY Dong, Y Si, ZY Wang… - Journal of the …, 2022 - ACS Publications
Understanding how the chiral or achiral section in chiral nanostructures contributes to
circularly polarized light emission (CPLE) at the atomic level is of fundamental importance …

Highly Efficient Circularly Polarized Luminescence from Chiral Au13 Clusters Stabilized by Enantiopure Monodentate NHC Ligands

P Luo, XJ Zhai, S Bai, YB Si, XY Dong… - Angewandte Chemie …, 2023 - Wiley Online Library
Chiral Au nanoclusters have promising application prospects in chiral sensing, asymmetric
catalysis, and chiroptics. However, enantiopure superatomic homogold clusters with …