Coherent two-dimensional and broadband electronic spectroscopies

S Biswas, JW Kim, X Zhang, GD Scholes - Chemical Reviews, 2022 - ACS Publications
Over the past few decades, coherent broadband spectroscopy has been widely used to
improve our understanding of ultrafast processes (eg, photoinduced electron transfer, proton …

Coherence in Chemistry: Foundations and Frontiers

JD Schultz, JL Yuly, EA Arsenault, K Parker… - Chemical …, 2024 - ACS Publications
Coherence refers to correlations in waves. Because matter has a wave-particle nature, it is
unsurprising that coherence has deep connections with the most contemporary issues in …

Simulating coherent multidimensional spectroscopy of nonadiabatic molecular processes: From the infrared to the x-ray regime

M Kowalewski, BP Fingerhut, KE Dorfman… - Chemical …, 2017 - ACS Publications
Crossings of electronic potential energy surfaces in nuclear configuration space, known as
conical intersections, determine the rates and outcomes of a large class of photochemical …

Progress and prospects in optical ultrafast microscopy in the visible spectral region: Transient absorption and two-dimensional microscopy

N Gross, CT Kuhs, B Ostovar, WY Chiang… - The Journal of …, 2023 - ACS Publications
Ultrafast optical microscopy, generally employed by incorporating ultrafast laser pulses into
microscopes, can provide spatially resolved mechanistic insight into scientific problems …

Characterizing mode anharmonicity and Huang–Rhys factors using models of femtosecond coherence spectra

MS Barclay, JS Huff, RD Pensack… - The Journal of …, 2022 - ACS Publications
Femtosecond laser pulses readily produce coherent quantum beats in transient–absorption
spectra. These oscillatory signals often arise from molecular vibrations and therefore may …

High-precision megahertz-to-terahertz dielectric spectroscopy of protein collective motions and hydration dynamics

A Charkhesht, CK Regmi… - The Journal of …, 2018 - ACS Publications
The low-frequency collective vibrational modes in proteins as well as the protein–water
interface have been suggested as dominant factors controlling the efficiency of biochemical …

Quantum and semiclassical dynamical studies of nonadiabatic processes in solution: achievements and perspectives

F Santoro, JA Green, L Martinez-Fernandez… - Physical Chemistry …, 2021 - pubs.rsc.org
We concisely review the main methodological approaches to model nonadiabatic dynamics
in isotropic solutions and their applications. Three general classes of models are identified …

Exciton polaron formation and hot-carrier relaxation in rigid Dion–Jacobson-type two-dimensional perovskites

S Biswas, R Zhao, F Alowa, M Zacharias… - Nature Materials, 2024 - nature.com
The efficiency of two-dimensional Dion–Jacobson-type materials relies on the complex
interplay between electronic and lattice dynamics; however, questions remain about the …

Observation of robust energy transfer in the photosynthetic protein allophycocyanin using single-molecule pump–probe spectroscopy

R Moya, AC Norris, T Kondo, GS Schlau-Cohen - Nature chemistry, 2022 - nature.com
Photosynthetic organisms convert sunlight to electricity with near unity quantum efficiency.
Absorbed photoenergy transfers through a network of chromophores positioned within …

Coupling between harmonic vibrations influences quantum beating signatures in two-dimensional electronic spectra

JD Schultz, T Kim, JP O'Connor… - The Journal of …, 2022 - ACS Publications
Launching and tracking wavepacket dynamics with two-dimensional electronic spectroscopy
(2DES) provides insight into the complex interactions that underlie coherent processes …