Healable and self-healing polyurethanes using dynamic chemistry

RH Aguirresarobe, S Nevejans, B Reck, L Irusta… - Progress in Polymer …, 2021 - Elsevier
Ever since the emergence of polymers, there has been interest in the production of “self-
healing” materials. Over the last decade this dream has become closer to reality with the …

Introducing dynamic bonds in light‐based 3D printing

G Zhu, HA Houck, CA Spiegel… - Advanced Functional …, 2024 - Wiley Online Library
Light‐based 3D printing has received significant attention due to several advantages
including high printing speed and resolution. Along with the development of new …

Closed-loop recyclable fully bio-based epoxy vitrimers from ferulic acid-derived hyperbranched epoxy resin

L Zhong, Y Hao, J Zhang, F Wei, T Li, M Miao… - …, 2022 - ACS Publications
Epoxy vitrimers with dynamic covalent networks enable reprocessing and recycling of epoxy
thermosets. However, achieving high mechanical performance remains a challenge. In this …

Sustainable photopolymers in 3D printing: a review on biobased, biodegradable, and recyclable alternatives

VSD Voet, J Guit, K Loos - Macromolecular Rapid …, 2021 - Wiley Online Library
The global market for 3D printing materials has grown exponentially in the last decade.
Today, photopolymers claim almost half of the material sales worldwide. The lack of …

Debondable adhesives and their use in recycling

KR Mulcahy, AFR Kilpatrick, GDJ Harper, A Walton… - Green …, 2022 - pubs.rsc.org
Structural adhesives are commonly used to join dissimilar materials and are of particular
interest in complex technological devices used in automotive, telecommunications, photonic …

Neighboring group participation and internal catalysis effects on exchangeable covalent bonds: application to the thriving field of vitrimer chemistry

F Cuminet, S Caillol, É Dantras, E Leclerc… - …, 2021 - ACS Publications
Vitrimers constitute a fascinating class of polymer materials that make the link between the
historically opposed 3D networks (thermosets) and linear polymers (thermoplastics). Their …

Sustainable materials and chemical processes for additive manufacturing

E Sanchez-Rexach, TG Johnston, C Jehanno… - Chemistry of …, 2020 - ACS Publications
Additive manufacturing (AM) is energizing the fields of chemistry and materials science to
develop new inks for new applications within fields such as aerospace, robotics, and …

High-performance and fully recyclable epoxy resins cured by imine-containing hardeners derived from vanillin and syringaldehyde

MA Rashid, S Zhu, L Zhang, K **, W Liu - European Polymer Journal, 2023 - Elsevier
Increasing concerns about environmental protection have driven the rapid development of
recyclable and sustainable thermosetting polymers. Herein, two biobased epoxy hardeners …

Biobased transesterification vitrimers

A Kumar, LA Connal - Macromolecular Rapid Communications, 2023 - Wiley Online Library
The rapid increase in the use of plastics and the related sustainability issues, including the
depletion of global petroleum reserves, have rightly sparked interest in the use of biobased …

High-Tg and Degradable Isosorbide-Based Polybenzoxazine Vitrimer

A Adjaoud, L Puchot, P Verge - ACS Sustainable Chemistry & …, 2021 - ACS Publications
This work describes new fully bio-based vitrimers prepared from isosorbide, a renewable
sugar-based chemical. Isosorbide was reacted with 4-hydroxypropionic acid …