[HTML][HTML] Artificial photosynthesis: molecular systems for catalytic water oxidation

MD Karkas, O Verho, EV Johnston… - Chemical reviews, 2014 - ACS Publications
The sustainable production of clean energy constitutes one of the most important scientific
challenges of the 21st century. Currently, the major part of the global energy supply is …

Molecular chromophore–catalyst assemblies for solar fuel applications

DL Ashford, MK Gish, AK Vannucci… - Chemical …, 2015 - ACS Publications
As the world's population increases, the US Department of Energy has estimated that energy
consumption will increase with it, increasing from 5.7× 1020 J in 2012 to 8.1× 1020 J in …

Finding the way to solar fuels with dye-sensitized photoelectrosynthesis cells

MK Brennaman, RJ Dillon, L Alibabaei… - Journal of the …, 2016 - ACS Publications
The dye-sensitized photoelectrosynthesis cell (DSPEC) integrates high bandgap,
nanoparticle oxide semiconductors with the light-absorbing and catalytic properties of …

Cobalt-oxide-based materials as water oxidation catalyst: recent progress and challenges

X Deng, H Tüysüz - AcS catalysis, 2014 - ACS Publications
Inspired by natural processes, there is an enormous interest in light-driven water splitting to
convert solar energy into electrical and chemical energy. This approach is thought to be able …

Visible-light initiated aerobic oxidations: a critical review

X Zhang, KP Rakesh, L Ravindar, HL Qin - Green Chemistry, 2018 - pubs.rsc.org
The development of new and highly efficient strategies for the rapid construction of
complicated molecular structures has huge implications and remains a preeminent goal in …

Ru (II) polypyridine complexes: photophysics, photochemistry, eletrochemistry, and chemiluminescence

A Juris, V Balzani, F Barigelletti, S Campagna… - Coordination Chemistry …, 1988 - Elsevier
Ru (bPY):+ has certainly been one of the molecules most extensively studied and most
widely used in research laboratories during the last ten years. A unique combination of …

A fast soluble carbon-free molecular water oxidation catalyst based on abundant metals

Q Yin, JM Tan, C Besson, YV Geletii, DG Musaev… - Science, 2010 - science.org
Traditional homogeneous water oxidation catalysts are plagued by instability under the
reaction conditions. We report that the complex [Co4 (H2O) 2 (PW9O34) 2] 10–, comprising …

Deactivation in homogeneous transition metal catalysis: causes, avoidance, and cure

RH Crabtree - Chemical reviews, 2015 - ACS Publications
Deactivation leads to loss of catalyst activity or selectivity with increasing reaction time, but
has attracted less academic attention in homogeneous catalysis than is justified by its …

Design and development of photoanodes for water-splitting dye-sensitized photoelectrochemical cells

JR Swierk, TE Mallouk - Chemical Society Reviews, 2013 - pubs.rsc.org
Dye sensitized solar cells (DSSCs) use low-cost materials, feature tunable molecular
sensitizers, and exhibit quantum efficiencies near unity. These advantageous features can …

Visible‐Light‐Mediated Decarboxylation/Oxidative Amidation of α‐Keto Acids with Amines under Mild Reaction Conditions Using O2

J Liu, Q Liu, H Yi, C Qin, R Bai, X Qi… - Angewandte Chemie …, 2014 - Wiley Online Library
Photochemistry has ushered in a new era in the development of chemistry, and photoredox
catalysis has become a hot topic, especially over the last five years, with the combination of …