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[HTML][HTML] Artificial photosynthesis: molecular systems for catalytic water oxidation
The sustainable production of clean energy constitutes one of the most important scientific
challenges of the 21st century. Currently, the major part of the global energy supply is …
challenges of the 21st century. Currently, the major part of the global energy supply is …
Molecular chromophore–catalyst assemblies for solar fuel applications
As the world's population increases, the US Department of Energy has estimated that energy
consumption will increase with it, increasing from 5.7× 1020 J in 2012 to 8.1× 1020 J in …
consumption will increase with it, increasing from 5.7× 1020 J in 2012 to 8.1× 1020 J in …
Finding the way to solar fuels with dye-sensitized photoelectrosynthesis cells
The dye-sensitized photoelectrosynthesis cell (DSPEC) integrates high bandgap,
nanoparticle oxide semiconductors with the light-absorbing and catalytic properties of …
nanoparticle oxide semiconductors with the light-absorbing and catalytic properties of …
Cobalt-oxide-based materials as water oxidation catalyst: recent progress and challenges
Inspired by natural processes, there is an enormous interest in light-driven water splitting to
convert solar energy into electrical and chemical energy. This approach is thought to be able …
convert solar energy into electrical and chemical energy. This approach is thought to be able …
Visible-light initiated aerobic oxidations: a critical review
The development of new and highly efficient strategies for the rapid construction of
complicated molecular structures has huge implications and remains a preeminent goal in …
complicated molecular structures has huge implications and remains a preeminent goal in …
Ru (II) polypyridine complexes: photophysics, photochemistry, eletrochemistry, and chemiluminescence
Ru (bPY):+ has certainly been one of the molecules most extensively studied and most
widely used in research laboratories during the last ten years. A unique combination of …
widely used in research laboratories during the last ten years. A unique combination of …
A fast soluble carbon-free molecular water oxidation catalyst based on abundant metals
Traditional homogeneous water oxidation catalysts are plagued by instability under the
reaction conditions. We report that the complex [Co4 (H2O) 2 (PW9O34) 2] 10–, comprising …
reaction conditions. We report that the complex [Co4 (H2O) 2 (PW9O34) 2] 10–, comprising …
Deactivation in homogeneous transition metal catalysis: causes, avoidance, and cure
RH Crabtree - Chemical reviews, 2015 - ACS Publications
Deactivation leads to loss of catalyst activity or selectivity with increasing reaction time, but
has attracted less academic attention in homogeneous catalysis than is justified by its …
has attracted less academic attention in homogeneous catalysis than is justified by its …
Design and development of photoanodes for water-splitting dye-sensitized photoelectrochemical cells
Dye sensitized solar cells (DSSCs) use low-cost materials, feature tunable molecular
sensitizers, and exhibit quantum efficiencies near unity. These advantageous features can …
sensitizers, and exhibit quantum efficiencies near unity. These advantageous features can …
Visible‐Light‐Mediated Decarboxylation/Oxidative Amidation of α‐Keto Acids with Amines under Mild Reaction Conditions Using O2
Photochemistry has ushered in a new era in the development of chemistry, and photoredox
catalysis has become a hot topic, especially over the last five years, with the combination of …
catalysis has become a hot topic, especially over the last five years, with the combination of …