Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

Playing with organic radicals as building blocks for functional molecular materials

I Ratera, J Veciana - Chemical Society Reviews, 2012 - pubs.rsc.org
The literature has shown numerous contributions on the synthesis and physicochemical
properties of persistent organic radicals but there are a lesser number of reports about their …

Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals

C Benelli, D Gatteschi - Chemical Reviews, 2002 - ACS Publications
Rare-earth ions are characterized by large unquenched orbital angular momentum
associated with the internal nature of the valence f orbitals. In fact, with the exception of …

A family of rare-earth-based single chain magnets: playing with anisotropy

K Bernot, L Bogani, A Caneschi… - Journal of the …, 2006 - ACS Publications
The first family of rare-earth-based single chain magnets is presented. Compounds of
general formula [M (hfac) 3 (NITPhOPh)], where M= Eu, Gd, Tb, Dy, Ho, Er, or Yb, and …

Systematic investigation of the nature of the coupling between a Ln (III) ion (Ln= Ce (III) to Dy (III)) and its aminoxyl radical ligands. structural and magnetic …

ML Kahn, JP Sutter, S Golhen… - Journal of the …, 2000 - ACS Publications
Numerous molecular compounds in which a paramagnetic Ln (III) ion is in interaction with a
second spin carrier such as a transition metal ion or an organic radical have been …

Magnetic anisotropy of dysprosium (III) in a low-symmetry environment: a theoretical and experimental investigation

K Bernot, J Luzon, L Bogani, M Etienne… - Journal of the …, 2009 - ACS Publications
A mixed theoretical and experimental approach was used to determine the local magnetic
anisotropy of the dysprosium (III) ion in a low-symmetry environment. The susceptibility …

Magnetism of metal-nitroxide compounds involving bis-chelating imidazole and benzimidazole substituted nitronyl nitroxide free radicals

D Luneau, P Rey - Coordination chemistry reviews, 2005 - Elsevier
Coordination compounds based on imidazole and benzimidazole substituted nitronyl
nitroxide radicals with transition metal ions and trivalent lanthanide ions are described from …

Analytical Determination of the {Ln–Aminoxyl Radical} Exchange Interaction Taking into Account Both the Ligand‐Field Effect and the Spin–Orbit Coupling of the …

ML Kahn, R Ballou, P Porcher, O Kahn… - … –A European Journal, 2002 - Wiley Online Library
Numerous compounds in which a paramagnetic LnIII ion is in an exchange interaction with a
second spin carrier, such as a transition metal ion or an organic radical, have been …

Nature of the Interaction between LnIII and CuII Ions in the Ladder-Type Compounds {Ln2[Cu(opba)]3}·S (Ln = Lanthanide Element; opba = ortho-Phenylenebis …

ML Kahn, C Mathonière, O Kahn - Inorganic chemistry, 1999 - ACS Publications
To date, most of the studies dealing with the magnetic properties of 4f− 3d compounds have
been limited to the case in which the 4f ion was GdIII, with a pure spin ground state. For the …

Slow magnetic relaxation and selective luminescent probe in a 2p–3d–4f heterotrispin chain

M Zhu, S Ma, H Dong, Q Zhong, Y Liu - CrystEngComm, 2023 - pubs.rsc.org
Three types of radical–3d/3d–4f heterotrispin complexes [(Cu (hfac) 2) 4 (NIT-4-OMe-4PyPh)
2](1),{[(Cu (hfac) 2) 3 (NIT-4-OMe-4PyPh) 2]} n (2) and {[Cu (hfac) 2][(NIT-4-OMe-4PyPh)] 2 …