Recent advances in the synthesis of luminescent tetra-coordinated boron compounds

AC Murali, P Nayak, K Venkatasubbaiah - Dalton Transactions, 2022 - pubs.rsc.org
Tetra-coordinated boron compounds offer a plethora of luminescent materials. Different
chelation around the boron center (O, O-, N, C-, N, O-, and N, N-) has been explored to tune …

Dearomatization of C6 Aromatic Hydrocarbons by Main Group Complexes

H Zhu, S Fujimori, A Kostenko… - Chemistry–A European …, 2023 - Wiley Online Library
The dearomatization reaction is a powerful method for transformation of simple aromatic
compounds to unique chemical architectures rapidly in synthetic chemistry. Over the past …

High‐Resolution Imaging of Latent Fingerprints through Near‐Infrared Organoboron AIEgens

L Liu, J Wang, X Wang, H Wang, M Li… - Chinese Journal of …, 2023 - Wiley Online Library
Comprehensive Summary A new class of near‐infrared (NIR) fluorescent organoboron
AIEgens was successfully developed for latent fingerprints (LFPs) imaging. They exhibit real …

Reversible Boron‐Insertion into Aromatic C− C Bonds

K Kuroki, T Ito, J Takaya - Angewandte Chemie, 2023 - Wiley Online Library
Abstract Formation of borabicyclo [3.2. 0] heptadiene derivatives was achieved via boron‐
insertion into aromatic C− C bonds in the photo‐promoted skeletal rearrangement reaction …

Tetra-coordinated boron-appended zinc (II)-salen: a highly selective fluorescence-based sensor for Sm3+ ions via sensitization

P Nayak, AC Murali, V Chandrasekhar… - Materials …, 2022 - pubs.rsc.org
Selective detection of metal ions is very important from the environmental and biological
points of view. In this regard, selective discrimination between lanthanide ions is very difficult …

Synthesis and stereochemistry of chiral aza-boraspirobifluorenes with tetrahedral boron-stereogenic centers

Y Yoshigoe, K Hashizume, S Saito - Dalton Transactions, 2022 - pubs.rsc.org
We have synthesized chiral aza-boraspirobifluorenes and evaluated their structural and
photophysical properties. Enantiomers were separated by chiral HPLC on a semi …

Synthesis, Photophysical, Electrochemical, and Non‐linear Optical Properties of Triaryl Pyrazole‐based B‐N Coordinated Boron Compounds

V Mukundam, S Sa, A Kumari… - Chemistry–An Asian …, 2022 - Wiley Online Library
We report here a set of triaryl pyrazole based B− N coordinated boron compounds (11‐17)
synthesized by electrophilic aromatic borylation strategy. All the pyrazole boron compounds …

Photoresponsive tetracoordinate arylboron smart molecules: Strategies for molecular design and photoresponse mechanisms

J Wang, M Li, H Gao, L **e, X Zheng, G Liu… - Smart …, 2024 - Wiley Online Library
Photoresponsive smart materials, which exhibit swift or instantaneous responses to external
light stimuli, are pivotal for advancing the development of novel smart devices. Among these …

Internal B← O Bond Facilitated Photo/Thermal Isomerization of Tetra-Coordinated Boranes

QD Zhou, GF Hu, S Sarfaraz, K Ayub, B **ao… - Inorganic …, 2023 - ACS Publications
A new series of O∧ C-chelate tetra-coordinated boranes with naphtha-aldehyde as the
chelate backbone have been synthesized. Their photophysical and photochemical …

Computational strategies for modelling excited states in organometallic chemistry

CP Souza, F Fantuzzi - 2024 - books.rsc.org
This chapter explores advanced computational methods and strategies to model excited
states in organometallic systems, essential for advancing discovery, design, and …