Reactions in single-molecule junctions

H Chen, C Jia, X Zhu, C Yang, X Guo… - Nature Reviews …, 2023 - nature.com
Develo** new materials is a long-standing goal that extends across the fields of synthesis,
catalysis, nanotechnology and materials science. Transforming one compound or material …

Structure and reactivity/selectivity control by oriented-external electric fields

S Shaik, R Ramanan, D Danovich… - Chemical Society …, 2018 - pubs.rsc.org
This is a tutorial on use of external-electric-fields (EEFs) as effectors of chemical change.
The tutorial instructs readers how to conceptualize and design electric-field effects on bonds …

Oriented electric fields as future smart reagents in chemistry

S Shaik, D Mandal, R Ramanan - Nature chemistry, 2016 - nature.com
Oriented external electric fields (OEEFs) as' smart reagents' are no longer a theoretical
dream. Here, we discuss the wide-ranging potential of using OEEFs to catalyse and control …

Harnessing electrostatic catalysis in single molecule, electrochemical and chemical systems: a rapidly growing experimental tool box

S Ciampi, N Darwish, HM Aitken, I Díez-Pérez… - Chemical Society …, 2018 - pubs.rsc.org
Static electricity is central to many day-to-day practical technologies, from separation
methods in the recycling of plastics to transfer inks in photocopying, but the exploration of …

Origins of non-ideal behaviour in voltammetric analysis of redox-active monolayers

BL Huffman, ARC Bredar, JL Dempsey - Nature Reviews Chemistry, 2024 - nature.com
Disorder in redox-active monolayers convolutes electrochemical characterization. This
disorder can come from pinhole defects, loose packing, heterogeneous distribution of redox …

Electrochemical and electrostatic cleavage of alkoxyamines

L Zhang, E Laborda, N Darwish, BB Noble… - Journal of the …, 2018 - ACS Publications
Alkoxyamines are heat-labile molecules, widely used as an in situ source of nitroxides in
polymer and materials sciences. Here we show that the one-electron oxidation of an …

Experimental evidence of long-lived electric fields of ionic liquid bilayers

M Belotti, X Lyu, L Xu, P Halat, N Darwish… - Journal of the …, 2021 - ACS Publications
Herein we demonstrate that ionic liquids can form long-lived double layers, generating
electric fields detectable by straightforward open circuit potential (OCP) measurements. In …

Oriented internal electrostatic fields: an emerging design element in coordination chemistry and catalysis

AB Weberg, RP Murphy, NC Tomson - Chemical Science, 2022 - pubs.rsc.org
The power of oriented electrostatic fields (ESFs) to influence chemical bonding and reactivity
is a phenomenon of rapidly growing interest. The presence of strong ESFs has recently …