Most high and medium oxidation state (OS≥ 3) metal and non-metal fluorides and oxide
fluorides have Lewis acidic properties, although detailed exploration of their chemistry with …

While most high and medium oxidation state (OS≥ 3) metal and non-metal fluorides and
oxide fluorides are strong Lewis acids, exploration of their coordination chemistry with …

Reaction of SnF2 in MeOH with the appropriate neutral N-or O-donor ligands produces [SnF
(2, 2′-bipy)] 2SnF6,[SnF (1, 10-phen)] 2SnF4 and [SnF2 (L)] L= Me3PO, dmso or pyNO) …

The development of several in situ generated catalyst systems for Ti-catalyzed oxidative
nitrene transfer reactions is reported. The simplest and widely applicable catalyst system …

Six-coordinate pseudo-octahedral complexes trans-[AlX2 (L–L) 2][AlX4](X= Cl, Br or I; L–L=
o-C6H4 (PMe2) 2, Me2P (CH2) 2PMe2) are produced from reaction of AlX3 with the …

The research of adamantane-type compounds has gained momentum in recent years,
yielding remarkable new applications for this class of materials. In particular, organic …

Group 4 Lewis acids are well-known catalysts and precursors for (non-aqueous) sol–gel
chemistry. Titanium, zirconium and hafnium halides, and alkoxy halides are precursors for …

The reaction of [GeF4L2], L= dmso (Me2SO), dmf (Me2NCHO), py (pyridine), pyNO (pyridine-
N-oxide), OPPh3, OPMe3, with Me3SiO3SCF3 (TMSOTf) and monodentate ligands, L, in a …

The reactions of the soft diphosphines o-C6H4 (PMe2) 2, Me2P (CH2) 2PMe2, Et2P (CH2)
2PEt2 or o-C6H4 (PPh2) 2 with NbF5 or TaF5 in anhydrous MeCN solution produce [MF4 …

[MF4 (dmso) 2](M= Zr or Hf) and [MF4 (dmf) 2], prepared by dissolving MF4· nH2O in the
appropriate solvent, have been used as synthons for a range of complexes of these …