N-Heterocyclic Carbenes in Materials Chemistry

CA Smith, MR Narouz, PA Lummis, I Singh… - Chemical …, 2019 - ACS Publications
N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of
ligands in molecular chemistry and have found applications in fields as varied as catalysis …

N-heterocyclic carbene coordinated metal nanoparticles and nanoclusters

H Shen, G Tian, Z Xu, L Wang, Q Wu, Y Zhang… - Coordination Chemistry …, 2022 - Elsevier
N-heterocyclic carbenes (NHCs) represent one of the most important organic ligands in
coordination chemistry, and have been recently attracting increasing attention in …

Chemical sensing with Au and Ag nanoparticles

V Montes-García, MA Squillaci… - Chemical Society …, 2021 - pubs.rsc.org
Noble metal nanoparticles (NPs) are ideal scaffolds for the fabrication of sensing devices
because of their high surface-to-volume ratio combined with their unique optical and …

Fundamentals and applications of N-heterocyclic carbene functionalized gold surfaces and nanoparticles

G Kaur, RL Thimes, JP Camden… - Chemical …, 2022 - pubs.rsc.org
The discovery of N-heterocyclic carbenes (NHCs) revolutionized organometallic chemistry
due to their strong metal–ligand bonds. These strong bonds also lend enhanced stability to …

Ultrastable and Highly Catalytically Active N‐Heterocyclic‐Carbene‐Stabilized Gold Nanoparticles in Confined Spaces

XX Gou, T Liu, YY Wang, YF Han - … Chemie International Edition, 2020 - Wiley Online Library
Controlling the size and surface functionalization of nanoparticles (NPs) can lead to
improved properties and applicability. Herein, we demonstrate the efficiency of the metal …

Photocatalytic hydrogen generation using colloidal covalent organic polymers decorated bimetallic Au-Pd nanoalloy (COPs/Pd-Au)

N Nouruzi, M Dinari, B Gholipour, N Mokhtari… - Molecular …, 2022 - Elsevier
Photocatalytic H 2 generation has been considered as an effective method for H 2
generation, in which the cocatalysts play a critical role. Here, we report highly reactive …

Robust gold nanorods stabilized by bidentate N-heterocyclic-carbene–thiolate ligands

MJ MacLeod, AJ Goodman, HZ Ye, HVT Nguyen… - Nature Chemistry, 2019 - nature.com
Although N-heterocyclic carbenes (NHCs) have demonstrated outstanding potential for use
as surface anchors, synthetic challenges have limited their application to either large planar …

Robust Water-Soluble Gold Nanoparticles via Polymerized Mesoionic N-Heterocyclic Carbene–Gold(I) Complexes

DTH Nguyen, M Bélanger-Bouliga, LR Shultz… - Chemistry of …, 2021 - ACS Publications
Gold nanomaterials have widespread applications across multiple areas of science and
technology. Sulfur-containing ligands (thiols and thioethers) have been traditionally used as …

Multifunctional gold nanorod for therapeutic applications and pharmaceutical delivery considering cellular metabolic responses, oxidative stress and cellular longevity

SM Mousavi, SA Hashemi, S Mazraedoost, K Yousefi… - Nanomaterials, 2021 - mdpi.com
Multifunctional gold nanorods (GNR) have drawn growing interest in biomedical fields
because of their excellent biocompatibility, ease of alteration, and special optical properties …

Why surface hydrophobicity promotes CO 2 electroreduction: a case study of hydrophobic polymer N-heterocyclic carbenes

Q Luo, H Duan, MC McLaughlin, K Wei, J Tapia… - Chemical …, 2023 - pubs.rsc.org
We report the use of polymer N-heterocyclic carbenes (NHCs) to control the
microenvironment surrounding metal nanocatalysts, thereby enhancing their catalytic …