Enabling heterogeneous catalysis to achieve carbon neutrality: Directional catalytic conversion of CO2 into carboxylic acids

X Zhang, W Huang, L Yu, M García‐Melchor… - Carbon …, 2024 - Wiley Online Library
The increase in anthropogenic carbon dioxide (CO2) emissions has exacerbated the
deterioration of the global environment, which should be controlled to achieve carbon …

Nonclassical routes for amide bond formation

RM De Figueiredo, JS Suppo, JM Campagne - Chemical reviews, 2016 - ACS Publications
The present review offers an overview of nonclassical (eg, with no pre-or in situ activation of
a carboxylic acid partner) approaches for the construction of amide bonds. The review aims …

Enantioselective chemo‐and biocatalysis: partners in retrosynthesis

M Hönig, P Sondermann, NJ Turner… - Angewandte Chemie …, 2017 - Wiley Online Library
Recent developments of stereoselective biocatalytic and chemocatalytic methods are
discussed. The review provides a guide to the use of biocatalytic methods in the area of …

Metal-catalysed approaches to amide bond formation

CL Allen, JMJ Williams - Chemical Society Reviews, 2011 - pubs.rsc.org
Amongst the many ways of constructing the amide bond, there has been a growing interest
in the use of metal-catalysed methods for preparing this important functional group. In this …

Metal-involving synthesis and reactions of oximes

DS Bolotin, NA Bokach, MY Demakova… - Chemical …, 2017 - ACS Publications
This review classifies and summarizes the past 10–15 years of advancements in the field of
metal-involving (ie, metal-mediated and metal-catalyzed) reactions of oximes. These …

Reactivity and stability of glucosinolates and their breakdown products in foods

FS Hanschen, E Lamy, M Schreiner… - Angewandte Chemie …, 2014 - Wiley Online Library
The chemistry of glucosinolates and their behavior during food processing is very complex.
Their instability leads to the formation of a bunch of breakdown and reaction products that …

Combination of a cyano migration strategy and alkene difunctionalization: the elusive selective azidocyanation of unactivated olefins

Z Wu, R Ren, C Zhu - Angewandte Chemie, 2016 - Wiley Online Library
A conceptually new, efficient, and metal‐free approach for the challenging azidocyanation of
unactivated alkenes is presented. The strategy of intramolecular distal cyano migration is …

Pd-catalyzed cross-couplings: On the importance of the catalyst quantity descriptors, mol% and ppm

CS Horbaczewskyj, IJS Fairlamb - Organic Process Research & …, 2022 - ACS Publications
This Review examines parts per million (ppm) palladium concentrations in catalytic cross-
coupling reactions and their relationship with mole percentage (mol%). Most studies in …

Chemistry from 3D printed objects

MR Hartings, Z Ahmed - Nature Reviews Chemistry, 2019 - nature.com
Abstract 3D printing technology has started to take hold as an enabling tool for scientific
advancement. Born from the marriage of computer-aided design and additive …

Metal Catalyzed One-Pot Synthesis of Tetrazines Directly from Aliphatic Nitriles and Hydrazine

J Yang, MR Karver, W Li, S Sahu… - … (International ed. in …, 2012 - pmc.ncbi.nlm.nih.gov
There is rapidly growing interest in the use of 1, 2, 4, 5-tetrazines as bioorthogonal coupling
agents.[1-3] Recent applications of tetrazine cycloadditions include intracellular small …